The immune system has evolved to survey and respond appropriately to the universe of foreign pathogens, deploying an intricate repertoire of mechanisms that keep responses to host tissues in check. The immune system is typically divided into two categories--innate and adaptive. Innate immunity refers to nonspecific defense mechanisms that come into play immediately or within hours of an antigen's appearance in the body. Adaptive immunity refers to antigen-specific immune response. The antigen first must be processed and recognized, and then the adaptive immune system creates an army of immune cells specifically designed to attack that antigen. For the adaptive immune system, specificity and sensitivity are provided by a large repertoire of antigen T-cell receptors (TCRs) constructed in their extracellular domain to recognize antigenic peptide fragments restricted and presented by histocompatibility complex molecules, and coupled through intracellular domains to signal transduction modules that serve to transmit environmental cues inside the cell.

Inflammation is triggered when innate immune cells detect infection or tissue injury. Pattern recognition receptors (PRRs) respond to pathogen-associated molecular patterns (PAMPs) or host-derived damage-associated molecular patterns (DAMPs) by triggering activation of NF-κB, AP1, CREB, c/EBP, and IRF transcription factors. Induction of genes encoding enzymes, chemokines, cytokines, adhesion molecules, and regulators of the extracellular matrix promotes the recruitment and activation of leukocytes. Besides resolving infection and injury, chronic inflammation is a risk factor for cancer.

Immunity has a major impact on inflammatory diseases and cancer, and biologics targeting immune cells and their factors. Immunosuppressant drugs suppress, or reduce, the strength of the body’s immune system, and have been used in the treatment of organ transplantation or autoimmunine diseases. Immunomodulator drugs have contributed to the significant improvement against cancer and other related diseases.

References:
[1] Sakaguchi S, et al. Immunol Cell Biol. 2012 Mar;90(3):277-87. doi: 10.1038/icb.2012.4.
[2] Newton K, et al. Cold Spring Harb Perspect Biol. 2012 Mar; 4(3): a006049.
[3] Bartneck M. Macromol Biosci. 2017 Apr 6. doi: 10.1002/mabi.201700021.


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Metyrosine

Metyrosine is a selective tyrosine hydroxylase enzyme inhibitor. Metyrosine exerts anti-inflammatory and anti-ulcerative effects. Metyrosine significantly inhibits high COX-2 activity[1]. Metyrosine is a very effective agent for blood pressure control[2].

  • CAS Number: 672-87-7
  • MF: C10H13NO3
  • MW: 195.21500
  • Catalog: COX
  • Density: 1.283g/cm3
  • Boiling Point: 383.7ºC at 760 mmHg
  • Melting Point: 320-340°C dec.
  • Flash Point: 185.9ºC

Immethridine 2HBr

Immethridine dihydrobromide is a selective histamine H3 receptor (H3R) agonist. Immethridine dihydrobromide displays 300-fold selectivity over the H4 receptor and does not bind to H1 or H2 receptors. Immethridine dihydrobromide can be used for experimental autoimmune encephalomyelitis (EAE) research[1].

  • CAS Number: 699020-93-4
  • MF: C9H11Br2N3
  • MW: 321.01200
  • Catalog: Histamine Receptor
  • Density: N/A
  • Boiling Point: N/A
  • Melting Point: N/A
  • Flash Point: N/A

Etoricoxib-13C,d3

Etoricoxib-13C,d3 is the 13C- and deuterium labeled. Etoricoxib (MK-0663) is a non steroidal anti-inflammatory agent, acting as a selective and orally active COX-2 inhibitor, with IC50s of 1.1 μM and 116 μM for COX-2 and COX-1 in human whole blood.

  • CAS Number: 2748267-73-2
  • MF: C1713CH12D3ClN2O2S
  • MW: 362.85
  • Catalog: COX
  • Density: N/A
  • Boiling Point: N/A
  • Melting Point: N/A
  • Flash Point: N/A

BMS-37

BMS-37 is a PD-1/PD-L1 immune checkpoint inhibitor. BMS-37 can be used as PD-L1 ligand to synthesize PROTAC molecules[1].

  • CAS Number: 1675202-20-6
  • MF: C27H32N2O4
  • MW: 448.55
  • Catalog: PD-1/PD-L1
  • Density: N/A
  • Boiling Point: N/A
  • Melting Point: N/A
  • Flash Point: N/A

STING agonist diABZI compound 2

STING agonist-4 is an stimulator of Interferon Genes (STING) receptor agonist with an apparent inhibitory constant (IC50) of 20 nM. STING agonist-4 is a two symmetry-related amidobenzimidazole (ABZI)-based compound to create linked ABZIs (diABZIs) with enhanced binding to STING and cellular function[1].

  • CAS Number: 2138300-40-8
  • MF: C34H38N12O4
  • MW: 678.74
  • Catalog: STING
  • Density: N/A
  • Boiling Point: N/A
  • Melting Point: N/A
  • Flash Point: N/A

Nω-Propyl-L-arginine

Nω-Propyl-L-arginine (N-omega-Propyl-L-arginine) is a potent, competitive, and highly selective inhibitor of neuronal nitric oxide synthase (nNOS), with a Ki of 57 nM. Nω-Propyl-L-arginine displays a 149-fold selectivity for nNOS over endothelial NOS (eNOS)[1][2].

  • CAS Number: 137361-05-8
  • MF: C9H20N4O2
  • MW: 216.281
  • Catalog: NO Synthase
  • Density: 1.2±0.1 g/cm3
  • Boiling Point: 411.0±55.0 °C at 760 mmHg
  • Melting Point: 122 °C(lit.)
  • Flash Point: 202.4±31.5 °C

IPG7236

IPG7236 is a selective CCR8 antagonist. IPG7236 exhibits significant tumor suppression in a mouse xenograft model of human breast cancer. IPG7236 can be used in cancer research[1].

  • CAS Number: 2756350-91-9
  • MF: C23H31N3O3S
  • MW: 429.58
  • Catalog: CCR
  • Density: N/A
  • Boiling Point: N/A
  • Melting Point: N/A
  • Flash Point: N/A

Flurbiprofen-13C,d3

Flurbiprofen-13C,d3 is the 13C- and deuterium labeled. Flurbiprofen (dl-Flurbiprofen) is a potent, orally active nonsteroidal anti-inflammatory agent (NSAIA/NSAID), with antipyretic and analgesic activities. Flurbiprofen is commonly used for the research of inflammatory diseases, including osteoarthritis and rheumatoid arthritis. Flurbiprofen is a non-selective cyclooxygenase (COX) inhibitor that can be used for the research of colorectal cancer[1][2][3].

  • CAS Number: 2747917-55-9
  • MF: C1413CH10D3FO2
  • MW: 248.27
  • Catalog: Apoptosis
  • Density: N/A
  • Boiling Point: N/A
  • Melting Point: N/A
  • Flash Point: N/A

INCB3344

INCB3344 is a potent, selective and orally bioavailable CCR2 antagonist with IC50 values of 5.1 nM (hCCR2) and 9.5 nM (mCCR2) in binding antagonism and 3.8 nM (hCCR2) and 7.8 nM (mCCR2) in antagonism of chemotaxis activity.

  • CAS Number: 1262238-11-8
  • MF: C29H34F3N3O6
  • MW: 577.59
  • Catalog: CCR
  • Density: N/A
  • Boiling Point: N/A
  • Melting Point: N/A
  • Flash Point: N/A

SKI-I

SKI-I is a potent and selective inhibitor of human sphingosine kinase (SK), with an IC50 of 1.2 μM for ST-hSK. SKI-I also inhibits hERK2 (IC50=11 μM). SKI-I induces apoptosis in tumor cell lines[1][2].

  • CAS Number: 306301-68-8
  • MF: C25H18N4O2
  • MW: 406.43600
  • Catalog: Apoptosis
  • Density: N/A
  • Boiling Point: N/A
  • Melting Point: N/A
  • Flash Point: N/A

IRAK4-IN-28

IRAK4-IN-28 (compound 42) is an orally active IRAK4 inhibitor (IC50=8.9 nM). IRAK4-IN-28 has binding affinity for IRAK4 with a Kd of 0.58 nM. IRAK4-IN-28 can be used in the research of inflammation and autoimmune diseases[1].

  • CAS Number: 2952532-92-0
  • MF: C27H31N9O3
  • MW: 529.59
  • Catalog: IRAK
  • Density: N/A
  • Boiling Point: N/A
  • Melting Point: N/A
  • Flash Point: N/A

Thioperamide

Thioperamide (MR-12842) is a potent, orally available, brain penetrant and selective H3 receptor antagonist with a Ki of 4.3 nM for inhibition of [3H]histamine release. Thioperamide inhibits [3H]histamine synthesis with a Ki of 31 nM[1].

  • CAS Number: 106243-16-7
  • MF: C15H24N4S
  • MW: 408.515
  • Catalog: Histamine Receptor
  • Density: 1.2 g/cm3
  • Boiling Point: 499.5ºC at 760 mmHg
  • Melting Point: N/A
  • Flash Point: 255.9ºC

Tetrahydrobiopterin

Tetrahydrobiopterin is a cofactor of the aromatic amino acid hydroxylases enzymes and also acts as an essential cofactor for all nitric oxide synthase (NOS) isoforms.

  • CAS Number: 17528-72-2
  • MF: C9H15N5O3
  • MW: 241.25
  • Catalog: NO Synthase
  • Density: 1.89g/cm3
  • Boiling Point: 506.6ºC at 760mmHg
  • Melting Point: N/A
  • Flash Point: 260.2ºC

SC-58125

SC-58125 is a potent and selective inhibitor of cyclooxygenase 2 (COX-2), with an IC50 of 0.04 μM. SC-58125 exhibits antitumor activity in vitro and in vivo, and it also can inhibit edema at the inflammatory site and is analgesic[1][2][3].

  • CAS Number: 162054-19-5
  • MF: C17H12F4N2O2S
  • MW: 384.348
  • Catalog: COX
  • Density: 1.4±0.1 g/cm3
  • Boiling Point: 512.6±50.0 °C at 760 mmHg
  • Melting Point: N/A
  • Flash Point: 263.8±30.1 °C

Trimethylamine oxide

Trimethylamine N-oxide is a gut microbe-dependent metabolite of dietary choline and other trimethylamine-containing nutrients. Trimethylamine N-oxide induces inflammation by activating the ROS/NLRP3 inflammasome. Trimethylamine N-oxide also accelerates fibroblast-myofibroblast differentiation and induces cardiac fibrosis by activating the TGF-β/smad2 signaling pathway[1][2][3].

  • CAS Number: 1184-78-7
  • MF: C3H9NO
  • MW: 75.110
  • Catalog: NOD-like Receptor (NLR)
  • Density: 0.9301 (rough estimate)
  • Boiling Point: 133.8°C (rough estimate)
  • Melting Point: 220-222ºC(lit.)
  • Flash Point: N/A

Gefurulimab

Gefurulimab (ALXN-1720) is a human-derived bispecific antibody against complement C5 and albumin that binds C5 and blocks its activation[1].

  • Density: N/A
  • Boiling Point: N/A
  • Melting Point: N/A
  • Flash Point: N/A

Brompheniramine Maleate

Brompheniramine maleate is a histamine H1 receptors antagonist.Target: Histamine H1 ReceptorBrompheniramine maleate, is an antihistamine drug of the propylamine (alkylamine) class. It is readily available over the counter and is indicated for the treatment of the symptoms of the common cold and allergic rhinitis. It is a first-generation antihistamine. Brompheniramine has antidepressant properties, inhibiting reuptake of the neurotransmitter serotonin. Based on this knowledge, Arvid Carlsson and his colleagues, working at the Swedish company Astra AB, were able to derive the first marketed selective serotonin reuptake inhibitor, zimelidine, from brompheniramine. Brompheniramine had a long half-life and large volume of distribution in normal adults. It also had a prolonged antihistaminic effect in the skin as evidenced by suppression of the wheal and flare response to histamine and by suppression of pruritus [1, 2].

  • CAS Number: 980-71-2
  • MF: C20H23BrN2O4
  • MW: 435.312
  • Catalog: Histamine Receptor
  • Density: N/A
  • Boiling Point: 403ºC at 760 mmHg
  • Melting Point: 134-135ºC
  • Flash Point: N/A

TLR1

TLR1 (compound 4a) is a low molecular weight, cell-penetrating Toll/IL-1 receptor/resistance (TIR) domain/BB-Loop mimic. TLR1 inhibits IL-1 receptor-mediated responses[1].

  • CAS Number: 566914-00-9
  • MF: C18H26N2O2
  • MW: 302.41100
  • Catalog: MyD88
  • Density: N/A
  • Boiling Point: N/A
  • Melting Point: N/A
  • Flash Point: N/A

Immuno modulator-1

Immuno modulator-1 (compound 22) inhibits TNFα and IL-2 secretion in human peripheral blood mononuclear cells (hPBMC), with IC50 values of 4.7 and 26 nM, respectively. Immuno modulator-1 shows hERG potassium channel blocking effect, with Inhibitory percentage of 20% at 3 μM[1].

  • CAS Number: 2757469-20-6
  • MF: C32H31FN6O4
  • MW: 582.62
  • Catalog: Interleukin Related
  • Density: N/A
  • Boiling Point: N/A
  • Melting Point: N/A
  • Flash Point: N/A

Buclizine

Buclizine is an orally active antihistamine antiallergic compound. Buclizine is a potent teratogen in the rat and shows anti-tumor activity[1][2][3].

  • CAS Number: 82-95-1
  • MF: C28H33ClN2
  • MW: 433.02800
  • Catalog: Histamine Receptor
  • Density: N/A
  • Boiling Point: N/A
  • Melting Point: N/A
  • Flash Point: N/A

Indomethacin sodium hydrate

Indomethacin sodium hydrate (Indometacin sodium hydrate) is a potent, blood-brain permeable and nonselective inhibitor of COX1 and COX2, with IC50s of 18 nM and 26 nM for human COX-1 and COX-2, respectively, in CHO cells[1]. Indomethacin sodium hydrate disrupts autophagic flux by disturbing the normal functioning of lysosomes[2].

  • CAS Number: 74252-25-8
  • MF: C19H21ClNNaO7
  • MW: 357.788
  • Catalog: Autophagy
  • Density: 1.3±0.1 g/cm3
  • Boiling Point: 499.4±45.0 °C at 760 mmHg
  • Melting Point: 162ºC
  • Flash Point: 255.8±28.7 °C

Vipoglanstat

Vipoglanstat (BI 1029539, GS-248), a carboxamide, is a potent and selective, non-peptide and orally active small molecular inhibitor of human prostaglandin E synthase 1 (mPGES-1). Vipoglanstat (BI 1029539, GS-248) also has anti-inflammatory activity[1][2].

  • CAS Number: 1360622-01-0
  • MF: C30H34Cl2F5N5O3
  • MW: 678.52
  • Catalog: PGE synthase
  • Density: N/A
  • Boiling Point: N/A
  • Melting Point: N/A
  • Flash Point: N/A

Mebhydrolin napadisylate

Mebhydrolin napadisylate is a specific histamine H1 receptor antagonist.

  • CAS Number: 6153-33-9
  • MF: C48H48N4O6S2
  • MW: 841.048
  • Catalog: Histamine Receptor
  • Density: 0.9799 (rough estimate)
  • Boiling Point: 457.3ºC at 760 mmHg
  • Melting Point: 280°C (rough estimate)
  • Flash Point: 230.4ºC

bendazol

Bendazol is a hypotensive drug which can also enhance NO synthase activity in renal glomeruli and collecting tubules.

  • CAS Number: 621-72-7
  • MF: C14H12N2
  • MW: 208.258
  • Catalog: NO Synthase
  • Density: 1.2±0.1 g/cm3
  • Boiling Point: 453.5±24.0 °C at 760 mmHg
  • Melting Point: 187ºC
  • Flash Point: 252.1±9.3 °C

Enerisant

Enerisant is a potent, highly selective, competitive and orally active histamine H3 receptor antagonist/inverse agonist with IC50s of 2.89 nM and 14.5 nM against human and rat histamine H3 receptors, respectively[1].

  • CAS Number: 1152747-82-4
  • MF: C22H30N4O3
  • MW: 398.499
  • Catalog: Histamine Receptor
  • Density: 1.2±0.1 g/cm3
  • Boiling Point: 586.2±50.0 °C at 760 mmHg
  • Melting Point: N/A
  • Flash Point: 308.3±30.1 °C

NLRP3 agonist 1

NLRP3 agonist 1 (compound 23) is a potent and orally active NLRP3 agonist. NLRP3 agonist 1 can activate the enzyme Caspase-1 to cleave pro-IL-1β and pro-IL-18 proinflammatory cytokines into their mature forms[1].

  • CAS Number: 2454019-69-1
  • MF: C15H16N6
  • MW: 280.33
  • Catalog: NOD-like Receptor (NLR)
  • Density: N/A
  • Boiling Point: N/A
  • Melting Point: N/A
  • Flash Point: N/A

Semapimod

Semapimod, an inhibitor of proinflammatory cytokine production, can inhibit TNF-α, IL-1β, and IL-6. Semapimod inhibits TLR4 signaling (IC50≈0.3 μM). Semapimod inhibits p38 MAPK and nitric oxide production in macrophages. Semapimod has potential in a variety of inflammatory and autoimmune disorders[1][2][3].

  • CAS Number: 352513-83-8
  • MF: C34H52N18O2
  • MW: 744.90
  • Catalog: Interleukin Related
  • Density: 1.39
  • Boiling Point: N/A
  • Melting Point: N/A
  • Flash Point: N/A

OSM-SMI-8

OSM-SMI-8 (NSC642624) is a potent OSM (oncostatin M) antagonist. OSM-SMI-8 has the potential for the research of cancer[1].

  • CAS Number: 1689690-20-7
  • MF: C28H20N2O4S2
  • MW: 512.60
  • Catalog: Interleukin Related
  • Density: N/A
  • Boiling Point: N/A
  • Melting Point: N/A
  • Flash Point: N/A

MK-0812 Succinate

MK-0812 Succinate is a potent and selective CCR2 antagonist with high affinity at CCR2 on human monocytes.

  • CAS Number: 851916-42-2
  • MF: C28H40F3N3O7
  • MW: 587.63
  • Catalog: CCR
  • Density: N/A
  • Boiling Point: N/A
  • Melting Point: N/A
  • Flash Point: N/A

TLR7 agonist 6

TLR7 agonist 6 (compound IIb-19) is an TLR7 agonist with an EC50 value of ~4 nM[1].

  • CAS Number: 2380231-86-5
  • MF: C27H30N6O3
  • MW: 486.57
  • Catalog: Toll-like Receptor (TLR)
  • Density: N/A
  • Boiling Point: N/A
  • Melting Point: N/A
  • Flash Point: N/A