MAPK families play an important role in complex cellular programs like proliferation, differentiation, development, transformation, and apoptosis. In mammalian cells, three MAPK families have been clearly characterized: namely classical MAPK (ERK), C-Jun N-terminal kinse/ stress-activated protein kinase (JNK/SAPK) and p38 kinase. Each MAPK-related cascade consists of no fewer than three enzymes that are activated in series: a MAPK kinase kinase (MAPKKK), a MAPK kinase (MAPKK) and a MAP kinase (MAPK).

The MAPK pathways are activated by diverse extracellular and intracellular stimuli including peptide growth factors, cytokines, hormones, and various cellular stressors. In the ERK signaling pathway, ERK1/2 is activated by MEK1/2, which is activated by Raf. Raf is activated by the Ras GTPase, whose activation is induced by RTKs such as the epidermal growth factor receptor. The JNK and p38 MAPK signaling pathways are activated by various types of cellular stress. The JNK pathway consists of JNK, a MAP2K such as MKK4 (SEK1) or MKK7, and a MAP3K such as ASK1, TAK1, MEKK1, or MLK3. In the p38 pathway, p38 is activated by MKK3 or MKK6, and these MAP2Ks are activated by the same MAP3Ks that function in the JNK pathway.

MAPK signaling pathways has been implicated in the development of many human diseases including Alzheimer's disease (AD), Parkinson's disease (PD), amyotrophic lateral sclerosis (ALS) and various types of cancers. Therefore, the development of small molecule drugs that selectively inhibit individual components of MAPK signaling pathways is a key therapeutic strategy for cancer and neurodegenerative disorders.

References:
[1] Zhang W, et al. Cell Research (2002) 12, 9-18.
[2] Kim EK, et al. Biochim Biophys Acta. 2010 Apr;1802(4):396-405.
[3] Kim EK, et al. Arch Toxicol. 2015 Jun;89(6):867-82.


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p38 Kinase inhibitor 4

p38 Kinase inhibitor 4 (compound 135) is a potent p38 inhibitor[1].

  • CAS Number: 13142-47-7
  • MF: C12H9Cl2N3O
  • MW: 282.13
  • Catalog: p38 MAPK
  • Density: N/A
  • Boiling Point: N/A
  • Melting Point: N/A
  • Flash Point: N/A

MW-150 hydrochloride

MW-150 hydrochloride (MW01-18-150SRM hydrochloride) is a selective inhibitor of p38αMAPK isoform with a ki of 101 nM[1].

  • CAS Number: 1923773-01-6
  • MF: C24H24ClN5
  • MW: 417.93
  • Catalog: p38 MAPK
  • Density: N/A
  • Boiling Point: N/A
  • Melting Point: N/A
  • Flash Point: N/A

Urolithin B

Urolithin B is one of the gut microbial metabolites of ellagitannins, and has anti-inflammatory and antioxidant effects. Urolithin B inhibits NF-κB activity by reducing the phosphorylation and degradation of IκBα, and suppresses the phosphorylation of JNK, ERK, and Akt, and enhances the phosphorylation of AMPK. Urolithin B is also a regulator of skeletal muscle mass[1][2].

  • CAS Number: 1139-83-9
  • MF: C13H8O3
  • MW: 212.20100
  • Catalog: AMPK
  • Density: 1.395g/cm3
  • Boiling Point: 432.6ºC at 760 mmHg
  • Melting Point: N/A
  • Flash Point: 196.6ºC

p38α inhibitor 3

p38α inhibitor 3 (Comp G7) is a p38α inhibitor that blocks the effectiveness of myoblast differentiation[1].

  • CAS Number: 260428-69-1
  • MF: C19H20FNO
  • MW: 297.3666032
  • Catalog: p38 MAPK
  • Density: 1.2±0.1 g/cm3
  • Boiling Point: 443.9±28.0 °C at 760 mmHg
  • Melting Point: N/A
  • Flash Point: 222.3±24.0 °C

TC13172

TC13172 is a mixed lineage kinase domain-like protein (MLKL) inhibitor with an EC50 value of 2 nM for HT-29 cells.

  • CAS Number: 2093393-05-4
  • MF: C17H16N4O5S
  • MW: 388.4
  • Catalog: Mixed Lineage Kinase
  • Density: N/A
  • Boiling Point: N/A
  • Melting Point: N/A
  • Flash Point: N/A

Antitumor agent-60

Antitumor agent-60 (compound 20) is a potent antitumor agent, targeting RAS-RAF signaling pathway and binding to CRAF with a Kd value of 3.93 μM. Antitumor agent-60 induces apoptosis by blocking cell cycle at G2/M phase. Antitumor agent-60 enhances the level of p53 and ROS. Antitumor agent-60 causes oval and irregular nucleus in cancer cells. Antitumor agent-60 can suppress the growth of tumor to some extent in A549 xenograft model[1].

  • CAS Number: 865784-65-2
  • MF: C24H28O10S
  • MW: 508.54
  • Catalog: Apoptosis
  • Density: N/A
  • Boiling Point: N/A
  • Melting Point: N/A
  • Flash Point: N/A

p38-α MAPK-IN-4

p38-α MAPK-IN-4 (Compound 69) is a selective p38α MAPK inhibitor with an IC50 of 1.5 µM. p38-α MAPK-IN-4 rapidly and strongly prevents the development of mechanical allodynia (MA) in vivo[1].

  • CAS Number: 2396754-57-5
  • MF: C17H13BrN2O
  • MW: 341.20
  • Catalog: p38 MAPK
  • Density: N/A
  • Boiling Point: N/A
  • Melting Point: N/A
  • Flash Point: N/A

Bohemine

Bohemine is a purine analogue and is a synthetic and selective CDK inhibitor with IC50s of 4.6 μM, 83 μM, and 2.7 μM for Cdk2/cyclin E, Cdk2/cyclin A, and Cdk9/cyclin T1, respectively. Bohemine also inhibits ERK2 with an IC50 of 52 μM and has less inhibitory effect on CDK1, CDK4 and CDK6. Bohemine has a broad spectrum anti-cancer activities[1][2].

  • CAS Number: 189232-42-6
  • MF: C18H24N6O
  • MW: 340.423
  • Catalog: CDK
  • Density: 1.3±0.1 g/cm3
  • Boiling Point: 589.4±60.0 °C at 760 mmHg
  • Melting Point: N/A
  • Flash Point: 310.3±32.9 °C

lithium O-acetylsalicylate

Aspirin (Acetylsalicylic Acid) lithium is an orally active, potent and irreversible inhibitor of cyclooxygenase COX-1 and COX-2, with IC50 values of 5 and 210 μg/mL, respectively. Aspirin lithium induces apoptosis. Aspirin lithium inhibits the activation of NF-κB. Aspirin lithium also inhibits platelet prostaglandin synthetase, and can prevent coronary artery and cerebrovascular thrombosis[1][2][3][4][5][6].

  • CAS Number: 552-98-7
  • MF: C9H7LiO4
  • MW: 186.09000
  • Catalog: Apoptosis
  • Density: N/A
  • Boiling Point: 321.4ºC at 760mmHg
  • Melting Point: N/A
  • Flash Point: 131.2ºC

ERK5-IN-4

ERK5-IN-4 (compound 34b) is a potent and selective inhibitor of extracellular signal-related kinase 5 (ERK5). ERK5-IN-4 inhibits ERK5 (full-length) and truncated ERK5 (ERK5 ΔTAD) kinase activity in HEK293 cells with an IC50 of 77 nM and 300 nM, respectively[1].

  • CAS Number: 1888305-17-6
  • MF: C16H11Cl2FN4O2
  • MW: 381.19
  • Catalog: ERK
  • Density: N/A
  • Boiling Point: N/A
  • Melting Point: N/A
  • Flash Point: N/A

FMK

FMK is a an irreversible RSK2 kinase inhibitor, that covalently modifies the C-terminal kinase domain of RSK.

  • CAS Number: 821794-92-7
  • MF: C18H19FN4O2
  • MW: 342.36700
  • Catalog: Ribosomal S6 Kinase (RSK)
  • Density: 1.36g/cm3
  • Boiling Point: 633.3ºC at 760 mmHg
  • Melting Point: N/A
  • Flash Point: 336.8ºC

LJI308

LJI308 is a new and potent pan-RSK inhibitor, with IC50 of 6 nM, 4 nM, and 13 nM for RSK1, RSK2, and RSK3, respectively.IC50 value: 6/4/13 nMTarget: RSK1/2/3in vitro: LJI308 efficiently inhibits RSK activity. LJI308 inhibites S6K1 with an IC50 of 0.8 μM, representing a 200-fold lower inhibition than that of RSK2. LJI308 inhibits MEK4 less than 50% at 10 μMand HIP kinase 1 less than 50% at 1 μM. [1] LJI308 inhibits the growth and survival of TNBC. LJI308 also suppresses the growth of HTRY-LT cells in 3-dimensional soft agar cultures. LJI308 is one of the first potent and effective targeted therapies for TNBC that, unlike currently utilized drugs, exhibits efficacy in eliminating the CSC population. [2]

  • CAS Number: 1627709-94-7
  • MF: C21H18F2N2O2
  • MW: 368.377
  • Catalog: Ribosomal S6 Kinase (RSK)
  • Density: 1.3±0.1 g/cm3
  • Boiling Point: 486.6±45.0 °C at 760 mmHg
  • Melting Point: N/A
  • Flash Point: 248.1±28.7 °C

S-99

ASK1-IN-5 (S-99) is an inhibitor of apoptosis signal-regulated kinase 1 (ASK1) and is useful in the study of autoimmune and neurodegenerative diseases[1].

  • CAS Number: 1124381-69-6
  • MF: C16H15F3N6O
  • MW: 364.33
  • Catalog: Apoptosis
  • Density: 1.5±0.1 g/cm3
  • Boiling Point: N/A
  • Melting Point: N/A
  • Flash Point: N/A

POP-3MB

POP-3MB (compound 1b) is an ICMT inhibitor (IC50: 2.5 μM). POP-3MB changes the subcellular localization of K-Ras and inhibits Ras activation. POP-3MB also inhibits Erk phosphorylation[1].

  • CAS Number: 1144114-27-1
  • MF: C38H39NO4S
  • MW: 605.79
  • Catalog: ERK
  • Density: N/A
  • Boiling Point: N/A
  • Melting Point: N/A
  • Flash Point: N/A

Cobimetinib

Cobimetinib (GDC-0973, RG7420) is a potent, selective and oral MEK inhibitor with an IC50 of 4.2 nM for MEK1.

  • CAS Number: 934660-93-2
  • MF: C21H21F3IN3O2
  • MW: 531.310
  • Catalog: MEK
  • Density: 1.7±0.1 g/cm3
  • Boiling Point: 565.9±50.0 °C at 760 mmHg
  • Melting Point: N/A
  • Flash Point: 296.1±30.1 °C

Sorafenib

Sorafenib (Bay 43-9006) is a potent multikinase inhibitor with IC50s of 6 nM, 20 nM, and 22 nM for Raf-1, B-Raf, and VEGFR-3, respectively.

  • CAS Number: 284461-73-0
  • MF: C21H16ClF3N4O3
  • MW: 464.825
  • Catalog: Autophagy
  • Density: 1.5±0.1 g/cm3
  • Boiling Point: 523.3±50.0 °C at 760 mmHg
  • Melting Point: 202-204°C
  • Flash Point: 270.3±30.1 °C

Pluripotin

Pluripotin is a dual inhibitor of ERK1 and RasGAP with KDs of 98 nM and 212 nM, respectively. Pluripotin also inhibits RSK1, RSK2, RSK3, and RSK4 with IC50s of 0.5, 2.5, 3.3, and 10.0 µM, respectively.

  • CAS Number: 839707-37-8
  • MF: C27H25F3N8O2
  • MW: 550.535
  • Catalog: ERK
  • Density: 1.4±0.1 g/cm3
  • Boiling Point: N/A
  • Melting Point: N/A
  • Flash Point: N/A

EMODICACID

Emodic acid (NSC624610) is an anthraquinone compound isolated from A. microcarpus, which can inhibit the proliferation of cancer cells by inhibiting the activity of NF-κB. Emodic acid can also inhibit the phosphorylation of p38, ERK and JNK, the secretion of tumor-promoting cytokines IL-1β and IL-6, and the expression of VEGF and MMP, thereby inhibiting the invasion and migration potential of cancer cells[1].

  • CAS Number: 478-45-5
  • MF: C15H8O7
  • MW: 300.22000
  • Catalog: ERK
  • Density: N/A
  • Boiling Point: N/A
  • Melting Point: N/A
  • Flash Point: N/A

CMK

CMK is a RSK2 kinase inhibitor which exhibits similar potency but less chemical stability compared with FMK.

  • CAS Number: 821794-90-5
  • MF: C18H19ClN4O2
  • MW: 358.822
  • Catalog: Ribosomal S6 Kinase (RSK)
  • Density: 1.4±0.1 g/cm3
  • Boiling Point: 647.5±55.0 °C at 760 mmHg
  • Melting Point: N/A
  • Flash Point: 345.4±31.5 °C

BRAF V600E/CRAF-IN-2

BRAF V600E/CRAF-IN-2 (Compound 9c) is a potent inhibitor of BRAF V600E/CRAF with IC50s of 0.888 and 0.229 μM, respectively. BRAF V600E/CRAF-IN-2 triggers apoptosis and cell cycle arrest at G0/G1 phase in HCT-116 colon cancer cell. BRAF V600E/CRAF-IN-2 has the potential for the research of cancer diseases[1].

  • CAS Number: 2499499-62-4
  • MF: C30H30F3N5O2
  • MW: 549.59
  • Catalog: Raf
  • Density: N/A
  • Boiling Point: N/A
  • Melting Point: N/A
  • Flash Point: N/A

AD57 (hydrochloride)

AD57 hydrochloride is an orally active multikinase inhibitor, inhibits RET, BRAF, S6K and Src[1].

  • CAS Number: 2320261-72-9
  • MF: C22H21ClF3N7O
  • MW: 491.897
  • Catalog: Raf
  • Density: N/A
  • Boiling Point: N/A
  • Melting Point: N/A
  • Flash Point: N/A

TAK-733

TAK-733 is a potent and selective MEK allosteric site inhibitor with an IC50 of 3.2 nM.

  • CAS Number: 1035555-63-5
  • MF: C17H15F2IN4O4
  • MW: 504.227
  • Catalog: MEK
  • Density: 1.9±0.1 g/cm3
  • Boiling Point: 530.5±60.0 °C at 760 mmHg
  • Melting Point: N/A
  • Flash Point: 274.6±32.9 °C

BMS-582949 (hydrochloride)

BMS-582949 hydrochloride is a novel highly selective p38α MAPK inhibitor, inhibits p38α with IC50 of 13 nM. IC50 value: 13 nM[1]Target: p38αin vitro: BMS-582949 does not significantly inhibit cytochrome P450 isozymes 1A2, 2C9, 2C19, and 2D6 with IC50values >40 μM. It is a weak inhibitor of CYP3A4, with an IC50 value ranging from 18 to 40 μM based in multiple tests. BMS-582949 displays >2000-fold selectivity for p38α over a diverse panel of 57 kinases that include serine kinases, nonreceptor tyrosine kinases, receptor tyrosine kinases, and the p38γ and δ isoforms. BMS-582949 is also 450-fold selective over Jnk2, a MAP kinase involved in inflammation, and 190-fold selective over Raf[1].BMS-582949 is a novel highly selective p38α MAPK inhibitor [2]. in vivo: The mouse clearance rate for BMS-582949 is 4.4 mL/min/kg. And, at an oral dose of 10 mg/kg, the mouse AUC0?8 h for BMS-582949 is 75.5 μM·h. BMS-582949 exhibited oral bioavailability values of 90% and 60% in mice and rats, respectively[1].

  • CAS Number: 912806-16-7
  • MF: C22H27ClN6O2
  • MW: 442.94200
  • Catalog: p38 MAPK
  • Density: N/A
  • Boiling Point: N/A
  • Melting Point: N/A
  • Flash Point: N/A

ERK-IN-7

ERK-IN-7 (Example 10), an analogue of SHR2415 (HY-151367), is a potent ERK inhibitor with IC50 of 5 nM and 7 nM against ERK1 and ERK2, respectively[1].

  • CAS Number: 2494010-63-6
  • MF: C22H20ClN7O2
  • MW: 449.89
  • Catalog: ERK
  • Density: N/A
  • Boiling Point: N/A
  • Melting Point: N/A
  • Flash Point: N/A

(2S,3S,4E)-2-Amino-4-octadecene-1,3-diol

L-threo-Sphingosine is a potent MAPK inhibitor. L-threo-Sphingosine induces apoptosis and clear DNA fragmentation. L-threo-Sphingosine shows anticancer effect[1].

  • CAS Number: 25695-95-8
  • MF: C18H37NO2
  • MW: 299.492
  • Catalog: Apoptosis
  • Density: 0.9±0.1 g/cm3
  • Boiling Point: 445.9±45.0 °C at 760 mmHg
  • Melting Point: N/A
  • Flash Point: 223.5±28.7 °C

IQ-1S

IQ-1 is a prospective inhibitor of NF-κB/activating protein 1 (AP-1) activity with an IC50 of 2.3±0.41 μM. IQ-1 has binding affinity (Kd values) in the nanomolar range for all three JNKs with Kds of 100 nM, 240 nM, and 360 nM for JNK3, JNK1, and JNK2, respectively.

  • CAS Number: 23146-22-7
  • MF: C15H9N3O
  • MW: 247.251
  • Catalog: JNK
  • Density: 1.4±0.1 g/cm3
  • Boiling Point: 511.8±43.0 °C at 760 mmHg
  • Melting Point: N/A
  • Flash Point: 263.3±28.2 °C

XMD8-92

XMD8-92 is a highly selective ERK5/BMK1 inhibitor with dissociation constant (Kd) value of 80 nM.

  • CAS Number: 1234480-50-2
  • MF: C26H30N6O3
  • MW: 474.555
  • Catalog: ERK
  • Density: 1.3±0.1 g/cm3
  • Boiling Point: 741.8±70.0 °C at 760 mmHg
  • Melting Point: N/A
  • Flash Point: 402.4±35.7 °C

GDC-0623

GDC-0623 is a potent, ATP-uncompetitive inhibitor of MEK1 (Ki=0.13 nM, +ATP), and displays 6-fold weaker potency against HCT116 (KRAS (G13D), EC50=42 nM) versus A375 (BRAFV600E, EC50=7 nM).

  • CAS Number: 1168091-68-6
  • MF: C16H14FIN4O3
  • MW: 456.210
  • Catalog: MEK
  • Density: 1.8±0.1 g/cm3
  • Boiling Point: N/A
  • Melting Point: N/A
  • Flash Point: N/A

SB203580

SB 203580 is a widely used p38 MAPK inhibitor with an IC50 of 0.3-0.5 μM. It shows more than 100-fold selectivity over PKB, LCK, and GSK-3β.

  • CAS Number: 152121-47-6
  • MF: C21H16FN3OS
  • MW: 377.435
  • Catalog: Autophagy
  • Density: 1.4±0.1 g/cm3
  • Boiling Point: 615.6±55.0 °C at 760 mmHg
  • Melting Point: 249 - 250ºC
  • Flash Point: 326.1±31.5 °C

EGFR/BRAFV600E-IN-1

EGFR/BRAFV600E-IN-1 (Compound 23) is a potent EGFR and BRAFV600E dual inhibitor with IC50s of 0.08 and 0.15 µM, respectively. EGFR/BRAFV600E-IN-1 induces apoptosis and cell cycle arrest in both pre-G1 and G2/M phases. EGFR/BRAFV600E-IN-1 exhibits antiproliferative activity againist A-549, MCF-7, Panc-1, HT-29 with IC50s of 1.2, 0.79, 1.3, and 1.23 µM, respectively[1].

  • CAS Number: 2492429-45-3
  • MF: C24H24ClN3O3
  • MW: 437.92
  • Catalog: Apoptosis
  • Density: N/A
  • Boiling Point: N/A
  • Melting Point: N/A
  • Flash Point: N/A