MAPK families play an important role in complex cellular programs like proliferation, differentiation, development, transformation, and apoptosis. In mammalian cells, three MAPK families have been clearly characterized: namely classical MAPK (ERK), C-Jun N-terminal kinse/ stress-activated protein kinase (JNK/SAPK) and p38 kinase. Each MAPK-related cascade consists of no fewer than three enzymes that are activated in series: a MAPK kinase kinase (MAPKKK), a MAPK kinase (MAPKK) and a MAP kinase (MAPK).

The MAPK pathways are activated by diverse extracellular and intracellular stimuli including peptide growth factors, cytokines, hormones, and various cellular stressors. In the ERK signaling pathway, ERK1/2 is activated by MEK1/2, which is activated by Raf. Raf is activated by the Ras GTPase, whose activation is induced by RTKs such as the epidermal growth factor receptor. The JNK and p38 MAPK signaling pathways are activated by various types of cellular stress. The JNK pathway consists of JNK, a MAP2K such as MKK4 (SEK1) or MKK7, and a MAP3K such as ASK1, TAK1, MEKK1, or MLK3. In the p38 pathway, p38 is activated by MKK3 or MKK6, and these MAP2Ks are activated by the same MAP3Ks that function in the JNK pathway.

MAPK signaling pathways has been implicated in the development of many human diseases including Alzheimer's disease (AD), Parkinson's disease (PD), amyotrophic lateral sclerosis (ALS) and various types of cancers. Therefore, the development of small molecule drugs that selectively inhibit individual components of MAPK signaling pathways is a key therapeutic strategy for cancer and neurodegenerative disorders.

References:
[1] Zhang W, et al. Cell Research (2002) 12, 9-18.
[2] Kim EK, et al. Biochim Biophys Acta. 2010 Apr;1802(4):396-405.
[3] Kim EK, et al. Arch Toxicol. 2015 Jun;89(6):867-82.


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BI-882370

BI-882370 is a potent and selective RAF kinase inhibitor that binds to the ATP binding site of the kinase positioned in the DFG-out (inactive) conformation of the BRAF kinase. BI-882370 (BI 882370) inhibits the oncogenic BRAFV600E-mutant, the WT BRAF and CRAF kinases with IC50s of 0.4, 0.8, and 0.6 nM, respectively. BI-882370 also inhibits SRC family kinases[1].

  • CAS Number: 1392429-79-6
  • MF: C28H33F2N7O2S
  • MW: 569.669
  • Catalog: Raf
  • Density: 1.4±0.1 g/cm3
  • Boiling Point: 666.8±65.0 °C at 760 mmHg
  • Melting Point: N/A
  • Flash Point: 357.0±34.3 °C

HPK1-IN-37

HPK1-IN-37 (compound A85) is an inhibitor of HPK1 (IC50=3.7 nM). HPK1-IN-37 can be used for research in HPK1 related disorders or diseases including cancers[1].

  • CAS Number: 2766481-68-7
  • MF: C27H35N7O4
  • MW: 521.61
  • Catalog: MAP4K
  • Density: N/A
  • Boiling Point: N/A
  • Melting Point: N/A
  • Flash Point: N/A

18:0-22:6 DG

18:0-22:6 DG (1-Stearoyl-2-docosahexaenoyl-sn-glycerol) is a diacylglycerol that can bind to RasGRP and modulate MAP kinases activation[1].

  • CAS Number: 65886-80-8
  • MF: C43H72O5
  • MW: 669.03
  • Catalog: p38 MAPK
  • Density: N/A
  • Boiling Point: N/A
  • Melting Point: N/A
  • Flash Point: N/A

(R)-PD 0325901CL

(R)-PD 0325901CL is an isomer of PD 0325901CL. PD 0325901CL is a selective inhibitor of mitogen-activated protein kinase kinase (MEK) involved in cancer research. PD 0325901CL inhibits the growth of cancer cells in vitro and in vivo[1].

  • CAS Number: 1003216-77-0
  • MF: C16H14ClF2IN2O4
  • MW: 498.64800
  • Catalog: MEK
  • Density: N/A
  • Boiling Point: N/A
  • Melting Point: N/A
  • Flash Point: N/A

Ravoxertinib

Ravoxertinib (GDC-0994) is an orally bioavailable ERK kinase inhibitor with an IC50 of 6.1 nM and 3.1 nM for ERK1 and ERK2, respectively.

  • CAS Number: 1453848-26-4
  • MF: C21H18ClFN6O2
  • MW: 440.858
  • Catalog: ERK
  • Density: 1.5±0.1 g/cm3
  • Boiling Point: 734.6±70.0 °C at 760 mmHg
  • Melting Point: N/A
  • Flash Point: 398.0±35.7 °C

Takinib

Takinib is a potent and selective TAK1 inhibitor with an IC50 of 9.5 nM.

  • CAS Number: 1111556-37-6
  • MF: C18H18N4O2
  • MW: 322.36
  • Catalog: MAP3K
  • Density: N/A
  • Boiling Point: N/A
  • Melting Point: N/A
  • Flash Point: N/A

PLX7922

PLX7922, a RAF inhibitor, can bind with BRAFV600E. PLX7922 inhibits pERK in BRAFV600E cell lines, and activates pERK in mutant NRAS cell lines[1].

  • CAS Number: 1638772-61-8
  • MF: C20H25FN6O2S2
  • MW: 464.58
  • Catalog: Raf
  • Density: N/A
  • Boiling Point: N/A
  • Melting Point: N/A
  • Flash Point: N/A

SB 706504

SB 706504 is a potent p38 MAPK inhibitor that inhibits Lipopolysaccharides (HY-D1056)-stimulated inflammatory gene expression in macrophages in chronic obstructive pulmonary disease (COPD)[1].

  • CAS Number: 911110-38-8
  • MF: C24H19F3N8O
  • MW: 492.456
  • Catalog: p38 MAPK
  • Density: N/A
  • Boiling Point: N/A
  • Melting Point: N/A
  • Flash Point: N/A

ROCK-IN-5

ROCK-IN-5 (compound I-B-37) is a potent inhibitor of ROCK, ERK, GSK, and AGC protein kinases. ROCK-IN-5 has the potential for proliferative, cardiac and neurodegenerative diseases research[1].

  • CAS Number: 692870-25-0
  • MF: C16H11ClFN3OS
  • MW: 347.79
  • Catalog: ROCK
  • Density: 1.4±0.1 g/cm3
  • Boiling Point: N/A
  • Melting Point: N/A
  • Flash Point: N/A

4'-Hydroxywogonin

4′-Hydroxywogonin (8-Methoxyapigenin), a flavonoid, could be isolated from a variety of plants including Scutellaria barbata and Verbena littoralis. 4′-Hydroxywogonin has anti-inflammatory activity via TAK1/IKK/NF-κB, MAPKs and PI3/AKT signaling pathways. 4′-Hydroxywogonin inhibits angiogenesis by disrupting PI3K/AKT signaling. 4′-Hydroxywogonin inhibits cell proliferation and induces apoptosis[1][2][3].

  • CAS Number: 57096-02-3
  • MF: C16H12O6
  • MW: 300.263
  • Catalog: Apoptosis
  • Density: 1.5±0.1 g/cm3
  • Boiling Point: 578.1±50.0 °C at 760 mmHg
  • Melting Point: N/A
  • Flash Point: 220.9±23.6 °C

p38 MAPK-IN-2

p38 MAPK-IN-2 is an inhibitor of p38 kinase.

  • CAS Number: 635725-16-5
  • MF: C20H19ClFN5O2
  • MW: 415.85
  • Catalog: p38 MAPK
  • Density: N/A
  • Boiling Point: N/A
  • Melting Point: N/A
  • Flash Point: N/A

Ralimetinib

Ralimetinib (LY2228820) is a potent and selective, ATP-competitive inhibitor of p38 MAPK α/β, with IC50s of 5.3 and 3.2 nM, respectively. Ralimetinib (LY2228820) selectively inhibits phosphorylation of MK2 (Thr334), with no effect on phosphorylation of p38α MAPK, JNK, ERK1/2, c-Jun, ATF2, or c-Myc[1].

  • CAS Number: 862505-00-8
  • MF: C24H29FN6
  • MW: 420.53
  • Catalog: p38 MAPK
  • Density: 1.2±0.1 g/cm3
  • Boiling Point: 634.4±65.0 °C at 760 mmHg
  • Melting Point: N/A
  • Flash Point: 337.5±34.3 °C

GSK1790627

GSK1790627 is the N-deacetylated metabolite of Trametinib (HY-10999). Trametinib is an orally active MEK inhibitor, and activates autophagy and induces apoptosis[1].

  • CAS Number: 871701-87-0
  • MF: C24H21FIN5O3
  • MW: 573.36
  • Catalog: MEK
  • Density: N/A
  • Boiling Point: N/A
  • Melting Point: N/A
  • Flash Point: N/A

Vemurafenib-d7

Vemurafenib-d7 is deuterium labeled Vemurafenib. Vemurafenib (PLX4032) is a first-in-class, selective, potent inhibitor of B-RAF kinase, with IC50s of 31 and 48 nM for RAFV600E and c-RAF-1, respectively[1][4]. Vemurafenib induces cell autophagy[5].

  • CAS Number: 1365986-73-7
  • MF: C23H11D7ClF2N3O3S
  • MW: 496.97
  • Catalog: Autophagy
  • Density: N/A
  • Boiling Point: N/A
  • Melting Point: N/A
  • Flash Point: N/A

B-Raf IN 10

B-Raf IN 10 (Compound C09) is a BRAF inhibitor with an IC50 between 50 and 100 nM. B-Raf IN 10 shows antitumor activity[1].

  • CAS Number: 1425485-87-5
  • MF: C22H21F3N4O4S
  • MW: 494.49
  • Catalog: Raf
  • Density: N/A
  • Boiling Point: N/A
  • Melting Point: N/A
  • Flash Point: N/A

Lidocaine HCl

Lidocaine hydrochloride hydrate (Lignocaine hydrochloride hydrate) inhibits sodium channels involving complex voltage and using dependence. Lidocaine hydrochloride hydrate decreases growth, migration and invasion of gastric carcinoma cells via up-regulating miR-145 expression and further inactivation of MEK/ERK and NF-κB signaling pathways. Lidocaine hydrochloride hydrate is an amide derivative and has potential for the research of ventricular arrhythmia[1][2].

  • CAS Number: 6108-05-0
  • MF: C14H25ClN2O2
  • MW: 288.814
  • Catalog: Apoptosis
  • Density: N/A
  • Boiling Point: 350.8ºC at 760 mmHg
  • Melting Point: 68.5ºC
  • Flash Point: 166ºC

Anticancer agent 164

CML-IN-1 (compound 7) is a potent anticancer agent. CML-IN-1 displays very good induced-apoptosis effect for human chronic myeloid leukemia (CML) cell line K562. CML-IN-1 exerts its effect via a significantly reduced protein phosphorylation of PI3K/Akt signal pathway. CML-IN-1 (compound 4) also inhibits cell proliferation by suppressing the MEK/ERK signaling pathway in colorectal cancer[1][2].

  • CAS Number: 2235393-30-1
  • MF: C21H23F3N8O2S2
  • MW: 540.58
  • Catalog: Apoptosis
  • Density: N/A
  • Boiling Point: N/A
  • Melting Point: N/A
  • Flash Point: N/A

ERK1/2 inhibitor 7

ERK1/2 inhibitor 7 is a potent ERK inhibitor with an IC50 of 0.94 nM for ERK2 (WO2021110168A1, WX006)[1].

  • CAS Number: 2648455-13-2
  • MF: C23H22FN7OS
  • MW: 463.53
  • Catalog: ERK
  • Density: N/A
  • Boiling Point: N/A
  • Melting Point: N/A
  • Flash Point: N/A

DEL 22379

DEL-22379 is an ERK dimerization Inhibitor. DEL-22379 readily binds to ERK2 with a Kd estimated in the low micromolar range, though binding is detectable even at low nanomolar concentrations. ERK2 dimerization is progressively inhibited with an IC50 of ~0.5 μM.

  • CAS Number: 181223-80-3
  • MF: C26H28N4O3
  • MW: 444.526
  • Catalog: ERK
  • Density: 1.3±0.1 g/cm3
  • Boiling Point: 763.9±60.0 °C at 760 mmHg
  • Melting Point: N/A
  • Flash Point: 415.8±32.9 °C

DL-Syringaresinol

DL-Syringaresinol ((±)-Syringaresinol), a lignin, inhibits UVA-induced upregulation of MMP-1 by suppressing MAPK/AP-1 signaling in human HaCaT keratinocytes and dermal fibroblasts (HDFs). DL-Syringaresinol has antiphotoaging properties against UVA-induced skin aging. DL-Syringaresinol exhibits weak antimycobacterial activity against Mycobacterium tuberculosis H37Rv[1][2].

  • CAS Number: 1177-14-6
  • MF: C22H26O8
  • MW: 418.437
  • Catalog: Bacterial
  • Density: 1.3±0.1 g/cm3
  • Boiling Point: 594.7±50.0 °C at 760 mmHg
  • Melting Point: N/A
  • Flash Point: 313.5±30.1 °C

CC-401

CC-401 hydrochloride is a potent inhibitor of all three forms of JNK with Ki of 25 to 50 nM.

  • CAS Number: 1438391-30-0
  • MF: C22H25ClN6O
  • MW: 424.927
  • Catalog: JNK
  • Density: N/A
  • Boiling Point: N/A
  • Melting Point: N/A
  • Flash Point: N/A

AS601245

AS601245 is a JNK Inhibitor with IC50s of 150, 220, and 70 nM for three JNK human isoforms (hJNK1, hJNK2, and hJNK3), respectively.

  • CAS Number: 345987-15-7
  • MF: C20H16N6S
  • MW: 372.44600
  • Catalog: JNK
  • Density: N/A
  • Boiling Point: N/A
  • Melting Point: N/A
  • Flash Point: N/A

Hydrangenol

Hydrangenol is an orally active antiphotoaging compound. It can be isolated from Hydrangea serrata leaves. Hydrangenol prevents wrinkle formation by reducing MMP and inflammatory cytokine expression and increasing moisturizing factors and antioxidant genes level[1].

  • CAS Number: 480-47-7
  • MF: C15H12O4
  • MW: 256.253
  • Catalog: COX
  • Density: 1.4±0.1 g/cm3
  • Boiling Point: 528.3±50.0 °C at 760 mmHg
  • Melting Point: N/A
  • Flash Point: 206.4±23.6 °C

AX 15836

AX-15836 is a potent and selective ERK5 inhibitor with an IC50 of 8 nM.

  • CAS Number: 2035509-96-5
  • MF: C32H40N8O5S
  • MW: 648.78
  • Catalog: ERK
  • Density: N/A
  • Boiling Point: N/A
  • Melting Point: N/A
  • Flash Point: N/A

Rhoifolin

Rhoifolin is a flavone glycoside isolated from Citrus grandis (L.) Osbeck leaves. Rhoifolin is beneficial for diabetic complications through enhanced adiponectin secretion, tyrosine phosphorylation of insulin receptor-β and glucose transporter 4 (GLUT 4) translocation[1]. Rhoifolin ameliorates titanium particle-stimulated osteolysis and attenuates osteoclastogenesis via RANKL-induced NF-κB and MAPK pathways[2].

  • CAS Number: 17306-46-6
  • MF: C27H30O14
  • MW: 578.519
  • Catalog: p38 MAPK
  • Density: 1.7±0.1 g/cm3
  • Boiling Point: 916.5±65.0 °C at 760 mmHg
  • Melting Point: N/A
  • Flash Point: 305.4±27.8 °C

B-Raf IN 8

B-Raf IN 8 (compound 7g) is a potent B-Raf inhibitor, with an IC50 of 70.65 nM. B-Raf IN 8 exhibits antitumor activity against hepatocellular carcinoma (HEPG-2), colon carcinoma (HCT-116), mammary gland (MCF-7) and human prostate cancer (PC-3) cells, with IC50 values of 9.78, 13.78, 18.52 and 29.85 µM[1].

  • CAS Number: 1215313-19-1
  • MF: C18H17N3O2
  • MW: 307.35
  • Catalog: Raf
  • Density: N/A
  • Boiling Point: N/A
  • Melting Point: N/A
  • Flash Point: N/A

n-methylbis(indol-3-yl)maleimide

Bisindolylmaleimide V is a cell-permeable negative control for protein kinase C inhibition studies with an IC50 value over 100 µM[1]. Bisindolylmaleimide V blocks the activation of mitogen-stimulated protein kinase p70s6k/p85s6k (S6K) in vivo with an IC50 of 8 µM[2].

  • CAS Number: 113963-68-1
  • MF: C21H15N3O2
  • MW: 341.363
  • Catalog: Ribosomal S6 Kinase (RSK)
  • Density: 1.5±0.1 g/cm3
  • Boiling Point: 655.7±55.0 °C at 760 mmHg
  • Melting Point: 271°C
  • Flash Point: 350.3±31.5 °C

PD0325901

PD0325901 is a selective and cell permeable MEK inhibitor with an IC50 of 0.33 nM.

  • CAS Number: 391210-10-9
  • MF: C16H14F3IN2O4
  • MW: 482.193
  • Catalog: Autophagy
  • Density: 1.8±0.1 g/cm3
  • Boiling Point: N/A
  • Melting Point: 112-114ºC
  • Flash Point: N/A

sertaconazole

Sertaconazole (FI7056 free base) is a broad-spectrum topical antifungal agent, exhibits anti-inflammatory activity via activation of a p38-COX-2-PGE2 pathway. Sertaconazole is also a microtubule inhibitor, shows antiproliferative effect, induces apoptosis and autophagy, and can also inhibit the migration of cells[1][2][3][4].

  • CAS Number: 99592-32-2
  • MF: C20H15Cl3N2OS
  • MW: 437.770
  • Catalog: Fungal
  • Density: 1.4±0.1 g/cm3
  • Boiling Point: 614.1±55.0 °C at 760 mmHg
  • Melting Point: N/A
  • Flash Point: 325.2±31.5 °C

Zeatin

(E/Z)-Zeatin is a plant cytokinin, which plays an important role in cell growth, differentiation, and division; (E/Z)-Zeatin also inhibits UV-induced MEK/ERK activation.

  • CAS Number: 13114-27-7
  • MF: C10H13N5O
  • MW: 219.24
  • Catalog: ERK
  • Density: 1.4±0.1 g/cm3
  • Boiling Point: 395.0±52.0 °C at 760 mmHg
  • Melting Point: N/A
  • Flash Point: 192.7±30.7 °C