Metabolic pathways are enzyme-mediated biochemical reactions that lead to biosynthesis (anabolism) or breakdown (catabolism) of natural product small molecules within a cell or tissue. In each pathway, enzymes catalyze the conversion of substrates into structurally similar products. Metabolic processes typically transform small molecules, but also include macromolecular processes such as DNA repair and replication, and protein synthesis and degradation. Metabolism maintains the living state of the cells and the organism.

Proteases are used throughout an organism for various metabolic processes. Proteases control a great variety of physiological processes that are critical for life, including the immune response, cell cycle, cell death, wound healing, food digestion, and protein and organelle recycling. On the basis of the type of the key amino acid in the active site of the protease and the mechanism of peptide bond cleavage, proteases can be classified into six groups: cysteine, serine, threonine, glutamic acid, aspartate proteases, as well as matrix metalloproteases. Proteases can not only activate proteins such as cytokines, or inactivate them such as numerous repair proteins during apoptosis, but also expose cryptic sites, such as occurs with β-secretase during amyloid precursor protein processing, shed various transmembrane proteins such as occurs with metalloproteases and cysteine proteases, or convert receptor agonists into antagonists and vice versa such as chemokine conversions carried out by metalloproteases, dipeptidyl peptidase IV and some cathepsins. In addition to the catalytic domains, a great number of proteases contain numerous additional domains or modules that substantially increase the complexity of their functions.

Imbalances in metabolic activities have been found to be critical in a number of pathologies, such as cardiovascular diseases, inflammation, cancer, and neurodegenerative diseases.

References:
[1] Turk B, et al. EMBO J. 2012 Apr 4;31(7):1630-43.
[2] Eatemadi A, et al. Biomed Pharmacother. 2017 Feb;86:221-231.


Anti-infection >
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Apoptosis >
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Metabolic Enzyme/Protease >
15-PGDH 5 alpha Reductase 5-Lipoxygenase Acetyl-CoA Carboxylase Acyltransferase Adenosine Deaminase Adenosine Kinase Aldehyde Dehydrogenase (ALDH) Aldose Reductase Aminopeptidase Angiotensin-converting Enzyme (ACE) ATGL ATP Citrate Lyase Carbonic Anhydrase Carboxypeptidase Cathepsin CETP COMT Cytochrome P450 Dipeptidyl Peptidase Dopamine β-hydroxylase E1/E2/E3 Enzyme Elastase Enolase FAAH FABP Factor Xa Farnesyl Transferase Fatty Acid Synthase (FAS) FXR Glucokinase GSNOR Gutathione S-transferase HCV Protease Hexokinase HIF/HIF Prolyl-Hydroxylase HIV Integrase HIV Protease HMG-CoA Reductase (HMGCR) HSP Indoleamine 2,3-Dioxygenase (IDO) Isocitrate Dehydrogenase (IDH) Lactate Dehydrogenase LXR MAGL Mineralocorticoid Receptor Mitochondrial Metabolism MMP Nampt NEDD8-activating Enzyme Neprilysin PAI-1 PDHK PGC-1α Phosphatase Phosphodiesterase (PDE) Phospholipase Procollagen C Proteinase Proteasome Pyruvate Kinase RAR/RXR Renin ROR Ser/Thr Protease SGK Stearoyl-CoA Desaturase (SCD) Thrombin Tryptophan Hydroxylase Tyrosinase Xanthine Oxidase
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PDE2/PDE10-IN-1

PDE2/PDE10-IN-1 is a phosphodiesterase 2 (PDE2) and PDE10 inhibitor with IC50s of 29 and 480 nM, respectively.

  • CAS Number: 1426833-08-0
  • MF: C15H10ClN5
  • MW: 295.73
  • Catalog: Phosphodiesterase (PDE)
  • Density: N/A
  • Boiling Point: N/A
  • Melting Point: N/A
  • Flash Point: N/A

Bigelovin

Bigelovin, a sesquiterpene lactone isolated from Inula helianthus-aquatica, is a selective retinoid X receptor α agonist. Bigelovin suppresses tumor growth through inducing apoptosis and autophagy via the inhibition of mTOR pathway regulated by ROS generation[1].

  • CAS Number: 3668-14-2
  • MF: C17H20O5
  • MW: 304.33800
  • Catalog: Apoptosis
  • Density: N/A
  • Boiling Point: N/A
  • Melting Point: N/A
  • Flash Point: N/A

Hydralazine hydrochloride

Hydralazine Hydrochloride is a direct-acting vasodilator that is used as an antihypertensive agent.Target: OthersHydralazine (apresoline) is a direct-acting smooth muscle relaxant used to treat hypertension by acting as a vasodilator primarily in arteries and arterioles. By relaxing vascular smooth muscle, vasodilators act to decrease peripheral resistance, thereby lowering blood pressure and decreasing afterload. However, this only has a short term effect on blood pressure, as the system will reset to the previous, high blood pressure necessary to maintain pressure in the kidney necessary for natriuresis. The long term effect of antihypertensive drugs comes from their effects on the pressure natriuresis curve. It belongs to the hydrazinophthalazine class of drugs [1]. Hydralazine may reduce blood pressure when compared to placebo in patients with primary hypertension, however this data is based on before and after studies, not RCTs. Furthermore, its effect on clinical outcomes remains uncertain [2].

  • CAS Number: 304-20-1
  • MF: C8H9ClN4
  • MW: 196.637
  • Catalog: HIF/HIF Prolyl-Hydroxylase
  • Density: N/A
  • Boiling Point: 491.9ºC at 760 mmHg
  • Melting Point: 273°C
  • Flash Point: 251.3ºC

Dansyl-Glu-Gly-Arg-chloromethylketone

Dansyl-Glu-Gly-Arg-Chloromethylketone is a protease inhibitor, and inhibits serine/threonine proteases. Dansyl-Glu-Gly-Arg-Chloromethylketone inhibits activated porcine factor IX[1].

  • CAS Number: 69024-84-6
  • MF: C26H36ClN7O7S
  • MW: 626.12
  • Catalog: Ser/Thr Protease
  • Density: N/A
  • Boiling Point: N/A
  • Melting Point: N/A
  • Flash Point: N/A

DNMDP

DNMDP is a potent and selective cancer cell cytotoxic agent that binds to PDE3A, promotes an interaction between PDE3A and Schlafen 12 (SLFN12); coexpression of SLFN12 with PDE3A correlates with DNMDP sensitivity, whereas depletion of SLFN12 results in decreased DNMDP sensitivity.

  • CAS Number: 328104-79-6
  • MF: C15H20N4O3
  • MW: 304.344
  • Catalog: Phosphodiesterase (PDE)
  • Density: 1.3±0.1 g/cm3
  • Boiling Point: N/A
  • Melting Point: N/A
  • Flash Point: N/A

Zifcasiran sodium

Zifcasiran sodium is a hypoxia-inducible factor (HIF) synthesis reducer. Zifcasiran sodium shows antitumor activities and can be used in advanced renal cell carcinoma research[1][2].

  • CAS Number: 2437257-12-8
  • MF: C737H929F20N211Na52O349P43S8
  • MW: 21491.26
  • Catalog: HIF/HIF Prolyl-Hydroxylase
  • Density: N/A
  • Boiling Point: N/A
  • Melting Point: N/A
  • Flash Point: N/A

OR-1896

OR-1896 is an active long-lived metabolite of Levosimendan. OR-1896 is a highly selective phosphodiesterase (PDE) III isoform inhibitor and a powerful vasodilator. OR-1896 can open ATP-sensitive K+ channels and has Ca2+-sensitizing effect. OR-1896 mitigates cardiomyocyte apoptosis, cardiac remodeling and myocardial inflammation[1].

  • CAS Number: 220246-81-1
  • MF: C13H15N3O2
  • MW: 245.27700
  • Catalog: Potassium Channel
  • Density: 1.278 g/cm3
  • Boiling Point: N/A
  • Melting Point: 224-226ºC
  • Flash Point: N/A

ISOGINKGETIN

Isoginkgetin is a MMP-9 inhibitor, also a Pre-mRNA Splicing Inhibitor with IC 50 of 30 uM.target : MMP-9 [1], Pre-mRNA Splicing [2]IC 50: 30 u M (Pre-mRNA Splicing)In vitro: Isoginkgetin inhibits HT1080 tumor cell invasion substantially. Isoginkgetin is also quite effective in inhibiting the activities of Akt and MMP-9 in MDA-MB-231 breast carcinomas and B16F10 melanoma. Isoginkgetin treatment result in marked decrease in invasion of these cells. isoginkgetin inhibit activities of both Akt and NF-κB. Isoginkgetin markedly decrease MMP-9 expression and invasion through inhibition of this pathway. [1] Splicing inhibition is the mechanistic basis of the anti-tumor activity of isoginkgetin. [2] Isoginkgetin inhibits tumor cell invasion by regulating phosphatidylinositol 3-kinase/Akt-dependent matrix metalloproteinase-9 expression. [3]

  • CAS Number: 548-19-6
  • MF: C32H22O10
  • MW: 566.511
  • Catalog: MMP
  • Density: 1.5±0.1 g/cm3
  • Boiling Point: 843.6±65.0 °C at 760 mmHg
  • Melting Point: 355ºC
  • Flash Point: 280.2±27.8 °C

BDBM32804

Antipain dihydrochloride is a protease inhibitor isolated from Actinomycetes. Antipain dihydrochloride inhibits N-methyl-N'-nitro-N-nitrosoguanidine (MNNG)-induced transformation and increases chromosomal aberrations. Antipain dihydrochloride restricts uterine DNA synthesis and function in mice[1][2][3][4].

  • CAS Number: 37682-72-7
  • MF: C27H46Cl2N10O6
  • MW: 677.623
  • Catalog: DNA/RNA Synthesis
  • Density: N/A
  • Boiling Point: N/A
  • Melting Point: N/A
  • Flash Point: N/A

Clemizole hydrochloride

Clemizole hydrochloride is an H1 histamine receptor antagonist, is found to substantially inhibit HCV replication. The IC50 of Clemizole for RNA binding by NS4B is 24±1 nM, whereas its EC50 for viral replication is 8 µM.

  • CAS Number: 1163-36-6
  • MF: C19H21Cl2N3
  • MW: 362.296
  • Catalog: HCV
  • Density: 1.25 g/cm3
  • Boiling Point: 506.1ºC at 760 mmHg
  • Melting Point: 241 °C
  • Flash Point: 259.9ºC

GK187

GK187 is a potent and selective Group VIA calcium-independent phospholipase A2 (GVIA iPLA2) inhibitor with an XI(50) value of 0.0001. GK187 can be used for researching various neurological disorders[1]. [The XI(50) is the mole fraction of the inhibitor in the total substrate interface required to inhibit the enzyme by 50%.]

  • CAS Number: 1071001-50-7
  • MF: C14H15F5O2
  • MW: 310.260
  • Catalog: Phospholipase
  • Density: 1.2±0.1 g/cm3
  • Boiling Point: 330.3±42.0 °C at 760 mmHg
  • Melting Point: N/A
  • Flash Point: 148.5±22.8 °C

Sildenafil

Sildenafil is a potent phosphodiesterase type 5 (PDE5) inhibitor with IC50 of 5.22 nM.

  • CAS Number: 139755-83-2
  • MF: C22H30N6O4S
  • MW: 474.576
  • Catalog: Autophagy
  • Density: 1.4±0.1 g/cm3
  • Boiling Point: 672.4ºC at 760 mmHg
  • Melting Point: 187-189°C
  • Flash Point: 360.5ºC

Suc-Ala-Ala-Pro-Abu-pNA trifluoroacetate salt

Suc-AAP-Abu-pNA (Colorimetric Elastase Substrate) is a specific substrate for pancreatic elastase (Km = 100 μM; Kcat/Km = 35,300 s-1 M-1 for rat pancreatic elastase; Km = 30 μM; Kcat/Km = 351,000 s-1 M-1 for porcine pancreatic elastase). Suc-AAP-Abu-pNA also promotes OPC migration[1].

  • CAS Number: 108392-27-4
  • MF: C25H34N6O9
  • MW: 562.572
  • Catalog: Elastase
  • Density: 1.4±0.1 g/cm3
  • Boiling Point: 1014.2±65.0 °C at 760 mmHg
  • Melting Point: N/A
  • Flash Point: 567.1±34.3 °C

BMS-262084

BMS-262084 is a potent, selective and irreversible inhibitor of factor XIa, with an IC50 of 2.8 nM against human factor XIa. BMS-262084 also inhibits human tryptase (IC50=5 nM). BMS-262084 exhibits antithrombotic effects[1][2].

  • CAS Number: 253174-92-4
  • MF: C18H31N7O5
  • MW: 425.48300
  • Catalog: Factor Xa
  • Density: N/A
  • Boiling Point: N/A
  • Melting Point: N/A
  • Flash Point: N/A

Xanthine oxidase-IN-9

Xanthine oxidase-IN-9 (Icarisids E) (Compound 2) is a potent xanthine oxidase (XOD) inhibitor with an IC50 of 31.81 μM[1].

  • CAS Number: 2571069-61-7
  • MF: C38H50O20
  • MW: 826.79
  • Catalog: Xanthine Oxidase
  • Density: N/A
  • Boiling Point: N/A
  • Melting Point: N/A
  • Flash Point: N/A

(Rac)-RK-682

(Rac)-RK-682, a racemate of RK-682, is a protein tyrosine phosphatases (PTPases) inhibitor. (Rac)-RK-682 inhibits protein tyrosine phosphatase 1B (PTP-1B), low molecular weight protein tyrosine phosphatases (LMW-PTP), and cell division cycle 25B (CDC-25B) with IC50s of 8.6 μM, 12.4 μM, and 0.7 μM, respectively[1].

  • CAS Number: 154639-24-4
  • MF: C21H36O5
  • MW: 368.51
  • Catalog: Phosphatase
  • Density: N/A
  • Boiling Point: N/A
  • Melting Point: N/A
  • Flash Point: N/A

Z-Phe-Ala-diazomethylketone

Z-Phe-Ala-diazomethylketone binds directly to Aβ42 monomers and small oligomers. Z-Phe-Ala-diazomethylketone inhibits the formation of Aβ42 dodecamers and inhibits Aβ42 fibril formation in the solution. Z-Phe-Ala-diazomethylketone has the potential for neurodegenerative disorders research[1].

  • CAS Number: 71732-53-1
  • MF: C21H22N4O4
  • MW: 394.42400
  • Catalog: Cathepsin
  • Density: N/A
  • Boiling Point: N/A
  • Melting Point: N/A
  • Flash Point: N/A

Xanthine oxidoreductase-IN-4

Xanthine oxidoreductase-IN-4 is an orally active xanthine oxidoreductase (XOR) inhibitor. Xanthine oxidoreductase-IN-4 has inhibitory activity against XOR with an IC50 value of 29.3 nM. Xanthine oxidoreductase-IN-4 can be used for the research of hyperuricemia[1].

  • CAS Number: 1026587-58-5
  • MF: C16H15N5O2
  • MW: 309.32
  • Catalog: Xanthine Oxidase
  • Density: N/A
  • Boiling Point: N/A
  • Melting Point: N/A
  • Flash Point: N/A

Tilorone dihydrochloride

Tilorone dihydrochloride is the first recognized synthetic, small molecular weight compound that is an orally active interferon inducer, used as an antiviral drug.

  • CAS Number: 27591-69-1
  • MF: C25H36Cl2N2O3
  • MW: 483.471
  • Catalog: HIF/HIF Prolyl-Hydroxylase
  • Density: 1.102g/cm3
  • Boiling Point: 552.3ºC at 760 mmHg
  • Melting Point: 230-233 °C(lit.)
  • Flash Point: 287.8ºC

3α-Aminocholestane

3α-Aminocholestane is a selective SH2 domain-containing inositol-5′-phosphatase 1 (SHIP1) inhibitor with an IC50 of ~2.5 μM.

  • CAS Number: 2206-20-4
  • MF: C27H49N
  • MW: 387.68466
  • Catalog: Phosphatase
  • Density: N/A
  • Boiling Point: N/A
  • Melting Point: 104.5-105.5℃ (methanol )
  • Flash Point: N/A

INCB13739

INCB13739 is an orally active, potent, selective and tissue-specific11β-HSD1 (11β-hydroxysteroid dehydrogenase 1) inhibitor, with IC50 values of 3.2 nM (11β-HSD1 enzymatic) and 1.1 nM (11β-HSD1 PBMC), respectively. INCB13739 can be used for type 2 diabetes mellitus (T2DM) and obesity research[1].

  • CAS Number: 869974-19-6
  • MF: C28H25N3O4
  • MW: 467.52
  • Catalog: Glucocorticoid Receptor
  • Density: N/A
  • Boiling Point: N/A
  • Melting Point: N/A
  • Flash Point: N/A

Tos-Gly-Pro-Lys-AMC trifluoroacetate salt

Tos-Gly-Pro-Lys-AMC is a fluorogenic peptide substrate of tryptase[1].

  • CAS Number: 128202-25-5
  • MF: C30H37N5O7S
  • MW: 611.70900
  • Catalog: Ser/Thr Protease
  • Density: N/A
  • Boiling Point: N/A
  • Melting Point: N/A
  • Flash Point: N/A

4-Butylresorcinol

4-Butylresorcinol is a phenol derivative which can inhibit tyrosinase with IC50 of 11.27 μM.

  • CAS Number: 18979-61-8
  • MF: C10H14O2
  • MW: 166.217
  • Catalog: Tyrosinase
  • Density: 1.1±0.1 g/cm3
  • Boiling Point: 300.7±12.0 °C at 760 mmHg
  • Melting Point: N/A
  • Flash Point: 144.5±14.2 °C

ML 265

TEPP-46 is a potent and selective pyruvate kinase M2 (PKM2) activator with an AC50 of 92 nM, showing little or no effect on PKM1, PKL and PKR.

  • CAS Number: 1221186-53-3
  • MF: C17H16N4O2S2
  • MW: 372.465
  • Catalog: Pyruvate Kinase
  • Density: 1.6±0.1 g/cm3
  • Boiling Point: 711.6±70.0 °C at 760 mmHg
  • Melting Point: N/A
  • Flash Point: 384.2±35.7 °C

Desoxyrhaponticin

Desoxyrhaponticin is a stilbene glycoside from the Tibetan nutritional food Rheum tanguticum Maxim. Desoxyrhaponticin is a Fatty acid synthase (FAS) inhibitor, and has apoptotic effect on human cancer cells[1].

  • CAS Number: 30197-14-9
  • MF: C21H24O8
  • MW: 404.410
  • Catalog: Apoptosis
  • Density: 1.4±0.1 g/cm3
  • Boiling Point: 700.5±60.0 °C at 760 mmHg
  • Melting Point: N/A
  • Flash Point: 377.5±32.9 °C

Lumigen APS 5

Lumigen APS-5 is a substrate of alkaline phosphatase (ALP). Lumigen APS-5 can be used to assess the activity of alkaline phosphatase (ALP)[1].

  • CAS Number: 193884-53-6
  • MF: C21H15ClNNa2O4PS
  • MW: 489.819
  • Catalog: Phosphatase
  • Density: N/A
  • Boiling Point: N/A
  • Melting Point: N/A
  • Flash Point: N/A

15-LOX-1 inhibitor 1

15-LOX-1 inhibitor 1 is a potent inhibitor of 15-LOX-1 (15-lipoxygenase-1) with an IC50 value of 0.19 μM. 15-LOX-1 inhibitor 1 protects macrophages from lipopolysaccharide-induced cytotoxicity. 15-LOX-1 inhibitor 1 inhibits NO formation and lipid peroxidation[1].

  • CAS Number: 2349374-37-2
  • MF: C22H21ClN2O4
  • MW: 412.866
  • Catalog: 5-Lipoxygenase
  • Density: 1.3±0.1 g/cm3
  • Boiling Point: 683.5±55.0 °C at 760 mmHg
  • Melting Point: N/A
  • Flash Point: 367.2±31.5 °C

Tosedostat-d5

Tosedostat-d5 (CHR-2797-d5) is the deuterium labeled Tosedostat. Tosedostat (CHR-2797) is an orally active aminopeptidase inhibitor. CHR-2797 exerts antiproliferative effects against a range of tumor cell lines[1][2].

  • CAS Number: 1217844-03-5
  • MF: C21H25D5N2O6
  • MW: 411.50
  • Catalog: Aminopeptidase
  • Density: N/A
  • Boiling Point: N/A
  • Melting Point: N/A
  • Flash Point: N/A

HIV-1 integrase inhibitor 2

HIV-1 integrase inhibitor, in the treatment of human immunodeficiency virus (HIV) infection.

  • CAS Number: 957890-42-5
  • MF: C21H20ClNO2
  • MW: 353.84200
  • Catalog: HIV
  • Density: N/A
  • Boiling Point: N/A
  • Melting Point: N/A
  • Flash Point: N/A

hCAII-IN-8

hCAII-IN-8, an amide, is a highly selective carbonic anhydrase (CA) inhibitor with an IC50 value of 0.18 μM against hCA II[1].

  • CAS Number: 952306-80-8
  • MF: C15H16N2O5S
  • MW: 336.36
  • Catalog: Carbonic Anhydrase
  • Density: N/A
  • Boiling Point: N/A
  • Melting Point: N/A
  • Flash Point: N/A