(1,5-Cyclohexadien-1-yloxy)(trimethyl)silane
(1,5-Cyclohexadien-1-yloxy)(trimethyl)silane structure
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Common Name | (1,5-Cyclohexadien-1-yloxy)(trimethyl)silane | ||
|---|---|---|---|---|
| CAS Number | 54781-19-0 | Molecular Weight | 168.308 | |
| Density | 0.9±0.1 g/cm3 | Boiling Point | 187.6±8.0 °C at 760 mmHg | |
| Molecular Formula | C9H16OSi | Melting Point | N/A | |
| MSDS | Chinese USA | Flash Point | 58.7±8.7 °C | |
| Symbol |
GHS02 |
Signal Word | Warning | |
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2-azabicyclo[2.2.2]octa-3,5-dione via a nitrile Diels-Alder reaction.
J. Org. Chem. 68(21) , 8256-7, (2003) The hetero-Diels-Alder reaction of an electron-deficient nitrile, p-toluenesulfonyl cyanide, with the silyl enol ether of cyclohexenone produced a hydrolytically sensitive [4 + 2] adduct in good yield. Use of Mander's reagent, ethyl cyanoformate, with the sam... |
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High-Temperature Diels-Alder Reactions: Transfer from Batch to Continuous Mode. Abele S, et al.
Org. Process Res. Dev. 16(5) , 1114-1120, (2011)
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Design and Scale-Up of Diels-Alder Reactions for the Practical Synthesis of 5-Phenylbicyclo [2.2. 2] oct-5-en-2-one. Funel JA, et al.
Org. Process Res. Dev. 15(6) , 1420-1427, (2011)
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Safety Assessment of Diels-Alder Reactions with Highly Reactive Acrylic Monomers. Abele S, et al.
Org. Process Res. Dev. 16(12) , 2015-2020, (2012)
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