2-(三甲硅烷氧基)-1,3-环己二烯
2-(三甲硅烷氧基)-1,3-环己二烯结构式
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常用名 | 2-(三甲硅烷氧基)-1,3-环己二烯 | 英文名 | (1,5-Cyclohexadien-1-yloxy)(trimethyl)silane |
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| CAS号 | 54781-19-0 | 分子量 | 168.308 | |
| 密度 | 0.9±0.1 g/cm3 | 沸点 | 187.6±8.0 °C at 760 mmHg | |
| 分子式 | C9H16OSi | 熔点 | N/A | |
| MSDS | 中文版 美版 | 闪点 | 58.7±8.7 °C | |
| 符号 |
GHS02 |
信号词 | Warning |
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2-azabicyclo[2.2.2]octa-3,5-dione via a nitrile Diels-Alder reaction.
J. Org. Chem. 68(21) , 8256-7, (2003) The hetero-Diels-Alder reaction of an electron-deficient nitrile, p-toluenesulfonyl cyanide, with the silyl enol ether of cyclohexenone produced a hydrolytically sensitive [4 + 2] adduct in good yield. Use of Mander's reagent, ethyl cyanoformate, with the sam... |
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High-Temperature Diels-Alder Reactions: Transfer from Batch to Continuous Mode. Abele S, et al.
Org. Process Res. Dev. 16(5) , 1114-1120, (2011)
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Design and Scale-Up of Diels-Alder Reactions for the Practical Synthesis of 5-Phenylbicyclo [2.2. 2] oct-5-en-2-one. Funel JA, et al.
Org. Process Res. Dev. 15(6) , 1420-1427, (2011)
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Safety Assessment of Diels-Alder Reactions with Highly Reactive Acrylic Monomers. Abele S, et al.
Org. Process Res. Dev. 16(12) , 2015-2020, (2012)
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