(1,5-Cyclohexadien-1-yloxy)(trimethyl)silane
(1,5-Cyclohexadien-1-yloxy)(trimethyl)silane structure
|
Common Name | (1,5-Cyclohexadien-1-yloxy)(trimethyl)silane | ||
|---|---|---|---|---|
| CAS Number | 54781-19-0 | Molecular Weight | 168.308 | |
| Density | 0.9±0.1 g/cm3 | Boiling Point | 187.6±8.0 °C at 760 mmHg | |
| Molecular Formula | C9H16OSi | Melting Point | N/A | |
| MSDS | Chinese USA | Flash Point | 58.7±8.7 °C | |
| Symbol |
GHS02 |
Signal Word | Warning | |
| Name | 1-(Trimethylsilyloxy)-3,4-dihydrobenzene |
|---|---|
| Synonym | More Synonyms |
| Density | 0.9±0.1 g/cm3 |
|---|---|
| Boiling Point | 187.6±8.0 °C at 760 mmHg |
| Molecular Formula | C9H16OSi |
| Molecular Weight | 168.308 |
| Flash Point | 58.7±8.7 °C |
| Exact Mass | 168.097046 |
| PSA | 9.23000 |
| LogP | 3.44 |
| Vapour Pressure | 0.9±0.3 mmHg at 25°C |
| Index of Refraction | 1.465 |
| Symbol |
GHS02 |
|---|---|
| Signal Word | Warning |
| Hazard Statements | H226 |
| Personal Protective Equipment | Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter |
| Hazard Codes | F+ |
| Risk Phrases | 10 |
| Safety Phrases | 16 |
| RIDADR | UN 1993 3/PG 3 |
| HS Code | 2931900090 |
|
~90%
(1,5-Cyclohexad... CAS#:54781-19-0 |
| Literature: Romanski, Steffen; Ruecker, Hannelore; Stamellou, Eleni; Guttentag, Miguel; Neudoerfl, Joerg-Martin; Alberto, Roger; Amslinger, Sabine; Yard, Benito; Schmalz, Hans-Guenther Organometallics, 2012 , vol. 31, # 16 p. 5800 - 5809 |
|
~64%
(1,5-Cyclohexad... CAS#:54781-19-0 |
| Literature: G.D. Searle and Co. Patent: US6046190 A1, 2000 ; US 6046190 A Title/Abstract Full Text Show Details G. D. Searle and Co. Patent: US5968942 A1, 1999 ; US 5968942 A |
|
~%
(1,5-Cyclohexad... CAS#:54781-19-0 |
| Literature: Acta Chemica Scandinavica, , vol. 43, # 2 p. 188 - 192 |
|
~%
(1,5-Cyclohexad... CAS#:54781-19-0 |
| Literature: Tetrahedron Letters, , vol. 22, # 23 p. 2151 - 2154 |
|
~50%
(1,5-Cyclohexad... CAS#:54781-19-0 |
| Literature: Noda, Daisuke; Sunada, Yusuke; Hatakeyama, Takuji; Nakamura, Masaharu; Nagashima, Hideo Chemical Communications, 2012 , vol. 48, # 100 p. 12231 - 12233 |
| Precursor 4 | |
|---|---|
| DownStream 10 | |
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CAS#:58753-28-9| HS Code | 2931900090 |
|---|---|
| Summary | 2931900090. other organo-inorganic compounds. VAT:17.0%. Tax rebate rate:13.0%. Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward). MFN tariff:6.5%. General tariff:30.0% |
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2-azabicyclo[2.2.2]octa-3,5-dione via a nitrile Diels-Alder reaction.
J. Org. Chem. 68(21) , 8256-7, (2003) The hetero-Diels-Alder reaction of an electron-deficient nitrile, p-toluenesulfonyl cyanide, with the silyl enol ether of cyclohexenone produced a hydrolytically sensitive [4 + 2] adduct in good yield... |
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High-Temperature Diels-Alder Reactions: Transfer from Batch to Continuous Mode. Abele S, et al.
Org. Process Res. Dev. 16(5) , 1114-1120, (2011)
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Design and Scale-Up of Diels-Alder Reactions for the Practical Synthesis of 5-Phenylbicyclo [2.2. 2] oct-5-en-2-one. Funel JA, et al.
Org. Process Res. Dev. 15(6) , 1420-1427, (2011)
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| (1,5-Cyclohexadien-1-yloxy)(trimethyl)silane |
| (Cyclohexa-1,5-dien-1-yloxy)(trimethyl)silane |
| 1,3-Cyclohexadiene, 2-[(trimethylsilyl)oxy]- |
| MFCD00274202 |
| cyclohexa-1,5-dien-1-yloxy(trimethyl)silane |