(1,5-Cyclohexadien-1-yloxy)(trimethyl)silane

[ Density]:
0.9±0.1 g/cm3

[ Boiling Point ]:
187.6±8.0 °C at 760 mmHg

[ Molecular Formula ]:
C₉H₁₆OSi

[ Molecular Weight ]:
168.308

[ Flash Point ]:
58.7±8.7 °C

[ Exact Mass ]:
168.097046

[ PSA ]:
9.23000

[ LogP ]:
3.44

[ Vapour Pressure ]:
0.9±0.3 mmHg at 25°C

[ Index of Refraction ]:
1.465

Click to get detail MSDS

[ Symbol ]:

GHS02

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H226

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
F+

[ Risk Phrases ]:
10

[ Safety Phrases ]:
16

[ RIDADR ]:
UN 1993 3/PG 3

[ HS Code ]:
2931900090

Click to get detail synthetic route

Precursor

DownStream

[ HS Code ]: 2931900090

[ Summary ]:
2931900090. other organo-inorganic compounds. VAT:17.0%. Tax rebate rate:13.0%. Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward). MFN tariff:6.5%. General tariff:30.0%

2-azabicyclo[2.2.2]octa-3,5-dione via a nitrile Diels-Alder reaction.

J. Org. Chem. 68(21) , 8256-7, (2003)

The hetero-Diels-Alder reaction of an electron-deficient nitrile, p-toluenesulfonyl cyanide, with the silyl enol ether of cyclohexenone produced a hydrolytically sensitive [4 + 2] adduct in good yield...

High-Temperature Diels-Alder Reactions: Transfer from Batch to Continuous Mode. Abele S, et al.

Org. Process Res. Dev. 16(5) , 1114-1120, (2011)

Design and Scale-Up of Diels-Alder Reactions for the Practical Synthesis of 5-Phenylbicyclo [2.2. 2] oct-5-en-2-one. Funel JA, et al.

Org. Process Res. Dev. 15(6) , 1420-1427, (2011)

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