Cyclooctane
Cyclooctane structure
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Common Name | Cyclooctane | ||
|---|---|---|---|---|
| CAS Number | 292-64-8 | Molecular Weight | 112.213 | |
| Density | 0.8±0.1 g/cm3 | Boiling Point | 152.0±0.0 °C at 760 mmHg | |
| Molecular Formula | C8H16 | Melting Point | 10-13 °C(lit.) | |
| MSDS | Chinese USA | Flash Point | 30.0±0.0 °C | |
| Symbol |
GHS02 |
Signal Word | Warning | |
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QSPR modeling of octanol/water partition coefficient for vitamins by optimal descriptors calculated with SMILES.
Eur. J. Med. Chem. 43 , 714-40, (2008) Simplified molecular input line entry system (SMILES) has been utilized in constructing quantitative structure-property relationships (QSPR) for octanol/water partition coefficient of vitamins and organic compounds of different classes by optimal descriptors.... |
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Evaluation of injection methods for fast, high peak capacity separations with low thermal mass gas chromatography.
J. Chromatogr. A. 1392 , 82-90, (2015) Low thermal mass gas chromatography (LTM-GC) was evaluated for rapid, high peak capacity separations with three injection methods: liquid, headspace solid phase micro-extraction (HS-SPME), and direct vapor. An Agilent LTM equipped with a short microbore capil... |
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Prediction of convulsant activity of gases and vapors.
Eur. J. Med. Chem. 44 , 885-90, (2009) The convulsant activity of 48 compounds studied by Eger et al. has been analyzed using an Abraham solvation equation. Four compounds identified by Eger et al. as more potent than expected were similarly identified, and for the remaining 44 compounds, the equa... |
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Two- and three-dimensional standing waves in a reaction-diffusion system.
Phys. Rev. E. Stat. Nonlin. Soft Matter Phys. 86(4 Pt 2) , 045202, (2012) We observe standing waves of chemical concentration in thin layers [quasi-two-dimensional (2D)] and capillaries [three-dimensional (3D)] containing the aqueous Belousov-Zhabotinsky reaction in a reverse microemulsion stabilized by the ionic surfactant sodium ... |
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Carbon-hydrogen activation of cycloalkanes by cyclopentadienylcarbonylrhodium--a lifetime enigma.
J. Am. Chem. Soc. 136(24) , 8614-25, (2014) Carbon-hydrogen bond activation reactions of four cycloalkanes (C5H10, C6H12, C7H14, and C8H16) by the Cp'Rh(CO) fragments (Cp' = η(5)-C5H5 (Cp) or η(5)-C5Me5 (Cp*)) were modeled theoretically by combining density functional and coupled cluster theories, and ... |
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Tetrazine ligation: fast bioconjugation based on inverse-electron-demand Diels-Alder reactivity.
J. Am. Chem. Soc. 130 , 13518-13519, (2008) Described is a bioorthogonal reaction that proceeds with unusually fast reaction rates without need for catalysis: the cycloaddition of s-tetrazine and trans-cyclooctene derivatives. The reactions tolerate a broad range of functionality and proceed in high yi... |
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Tetradentate Schiff base ligands and their complexes: synthesis, structural characterization, thermal, electrochemical and alkane oxidation.
Spectrochim. Acta. A. Mol. Biomol. Spectrosc. 95 , 382-98, (2012) Three Schiff base ligands (H(2)L(1)-H(2)L(3)) with N(2)O(2) donor sites were synthesized by condensation of 1,5-diaminonapthalene with benzaldehyde derivatives. A series of Cu(II), Co(II), Ni(II), Mn(II) and Cr(III) complexes were prepared and characterized b... |
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Topology of cyclo-octane energy landscape.
J. Chem. Phys. 132(23) , 234115, (2010) Understanding energy landscapes is a major challenge in chemistry and biology. Although a wide variety of methods have been invented and applied to this problem, very little is understood about the actual mathematical structures underlying such landscapes. Pe... |
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Membrane labeling and immobilization via copper-free click chemistry.
Chem. Commun. (Camb.) 48(10) , 1431-3, (2012) Copper-free click chemistry was employed to derivatize membrane bilayers. This approach uses an azido-lipid conjugate presented on liposomes, which can be labeled in bioorthogonal fashion via cyclooctyne-tagged reagents. An immobilization-based approach using... |
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From common carbohydrates to enantiopure cyclooctane polyols and glycomimetics via deoxygenative zirconocene ring contraction.
J. Org. Chem. 71(12) , 4353-63, (2006) D-Arabinose and D-glucose are transformed into the identical vinyl furanoside, whose role is to serve as the precursor to enantiopure cyclooctadienone 6. The key steps of this relay involve a zirconocene-promoted ring contraction and [3,3] sigmatropic rearran... |