4-Trifluoromethylphenylboronic acid
4-Trifluoromethylphenylboronic acid structure
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Common Name | 4-Trifluoromethylphenylboronic acid | ||
|---|---|---|---|---|
| CAS Number | 128796-39-4 | Molecular Weight | 189.93 | |
| Density | 1.4±0.1 g/cm3 | Boiling Point | 258.6±50.0 °C at 760 mmHg | |
| Molecular Formula | C7H6BF3O2 | Melting Point | 245-250 °C(lit.) | |
| MSDS | Chinese USA | Flash Point | 110.2±30.1 °C | |
| Symbol |
GHS07 |
Signal Word | Warning | |
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Ruthenium(0)-catalyzed sp3 C-H bond arylation of benzylic amines using arylboronates.
Org. Lett. 7th ed., 14 , 1930-1933, (2012) A Ru-catalyzed direct arylation of benzylic sp(3) carbons of acyclic amines with arylboronates is reported. This highly regioselective and efficient transformation can be performed with various combinations of N-(2-pyridyl) substituted benzylamines and arylbo... |
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Tandem-type Pd(II)-catalyzed oxidative Heck reaction/intramolecular C-H amidation sequence: a novel route to 4-aryl-2-quinolinones.
Chem. Commun. (Camb.) 36th ed., 48 , 4332-4334, (2012) A novel catalytic method for synthesizing 4-aryl-2-quinolinones is reported. The process involves two mechanistically independent, sequential Pd(II)-catalyzed reactions--the oxidative Heck reaction and the intramolecular C-H amidation--both of which smoothly ... |
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Combined experimental-theoretical NMR study on 2,5-bis(5-aryl-3-hexylthiophen-2-yl)-thiazolo[5,4-d]thiazole derivatives for printable electronics.
Magn. Reson. Chem. 5th ed., 50 , 379-387, (2012) Four 2,5-bis(5-aryl-3-hexylthiophen-2-yl)thiazolo[5,4-d]thiazole derivatives have been synthesized and thoroughly characterized. The extended aromatic core of the molecules was designed to enhance the charge transport characteristics, and solubilizing hexyl s... |
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An efficient base-free N-arylation of imidazoles and amines with arylboronic acids using copper-exchanged fluorapatite.
J. Org. Chem. 71 , 9522, (2006) N-Arylation of imidazoles and amines with arylboronic acids was accomplished with copper-exchanged fluorapatite (CuFAP) in methanol at room temperature. The products N-arylimidazoles and N-arylamines were isolated in good to excellent yields. A variety of ary... |
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Synthesis of terphenyl benzimidazoles as tubulin polymerization inhibitors.
Eur. J. Med. Chem. 50 , 9-17, (2012) A series of new terphenyl benzimidazoles (3a-z and 3aa-ad) were synthesized and evaluated for their anticancer activity. All the 30 compounds have shown moderate to good anticancer potency, however some of the compounds (3j, 3m-t and 3aa-ad) exhibited promine... |
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Efficient [5 + 1]-strategy for the assembly of 1,8-naphthyridin-4(1H)-ones by domino amination/conjugate addition reactions of 1-(2-chloropyridin-3-yl)prop-2-yn-1-ones with amines.
Org. Biomol. Chem. 15th ed., 10 , 2955-2959, (2012) A facile synthetic approach for the synthesis of 1,8-naphthyridine-4(1H)-one derivatives via a catalyst free and Pd-supported tandem amination sequence is developed and described. In a case of aliphatic amines reaction proceeds in a catalyst free mode, howeve... |
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A new access to 3-substituted-1(2H)-isoquinolone by tandem palladium-catalyzed intramolecular aminocarbonylation annulation.
Org. Biomol. Chem. 13th ed., 10 , 2683-2691, (2012) An original tribromide derivative based, palladium-catalyzed synthesis of 3-substituted-1(2H)-isoquinolone is described based on a regioselective Suzuki-Miyaura C-C coupling on o-halo-(2,2-dihalovinyl)-benzene followed by a palladium catalyzed amination-carbo... |
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Pd-catalyzed direct arylation of phenylpyrazole: Synthesis of fipronil derivatives with aryl boronic acids promoted by a stoichiometric amount of NIS Zhang, X-H.; Han, J-S.; Zhong, P.
J. Fluor. Chem. 137 , 44-49, (2012)
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Ligand-free copper-catalyzed coupling of nitroarenes with arylboronic acids Zhang, J.; et al.
Green Chem. 4th ed., 14 , 912-916, (2012)
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Regioselective Arylation and Alkynylation of 2,3-Dibromo-1H-inden-1-one by Suzuki-Miyaura and Sonogashira Cross-Coupling Reactions Khera, R. A.; et al.
Helv. Chim. Acta 3rd ed., 95 , 469-482, (2012)
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