Palladium, [1,1'-(1R)-[1,1'-binaphthalene]-2,2'-diylbis[1,1-diphenylphosphine-κP]]dibromo-, (SP-4-2)

Palladium, [1,1'-(1R)-[1,1'-binaphthalene]-2,2'-diylbis[1,1-diphenylphosphine-κP]]dibromo-, (SP-4-2) Structure
Palladium, [1,1'-(1R)-[1,1'-binaphthalene]-2,2'-diylbis[1,1-diphenylphosphine-κP]]dibromo-, (SP-4-2) structure
Common Name Palladium, [1,1'-(1R)-[1,1'-binaphthalene]-2,2'-diylbis[1,1-diphenylphosphine-κP]]dibromo-, (SP-4-2)
CAS Number 923987-15-9 Molecular Weight 888.90000
Density N/A Boiling Point N/A
Molecular Formula C44H32Br2P2Pd Melting Point N/A
MSDS Chinese USA Flash Point N/A
Symbol GHS07
GHS07
Signal Word Warning

Stable preformed chiral palladium catalysts for the one-pot asymmetric reductive amination of ketones.

Org. Lett. 11 , 265-268, (2009)

The application of air stable preformed [(R)-BINAP]PdBr2, [(S)-BINAP]PdBr2, [(R)-Tol-BINAP]PdBr2, and [(S,S)-CHIRAPHOS]PdBr2 complexes in the one-pot asymmetric reductive amination of various carbonyl compounds, leading to chiral amines in very good yields wi...