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Palladium, [1,1'-(1R)-[1,1'-binaphthalene]-2,2'-diylbis[1,1-diphenylphosphine-κP]]dibromo-, (SP-4-2)

Palladium, [1,1'-(1R)-[1,1'-binaphthalene]-2,2'-diylbis[1,1-diphenylphosphine-κP]]dibromo-, (SP-4-2)结构式
Palladium, [1,1'-(1R)-[1,1'-binaphthalene]-2,2'-diylbis[1,1-diphenylphosphine-κP]]dibromo-, (SP-4-2)结构式
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常用名 Palladium, [1,1'-(1R)-[1,1'-binaphthalene]-2,2'-diylbis[1,1-diphenylphosphine-κP]]dibromo-, (SP-4-2) 英文名 Palladium, [1,1'-(1R)-[1,1'-binaphthalene]-2,2'-diylbis[1,1-diphenylphosphine-κP]]dibromo-, (SP-4-2)
CAS号 923987-15-9 分子量 888.90000
密度 N/A 沸点 N/A
分子式 C44H32Br2P2Pd 熔点 N/A
MSDS 中文版 美版 闪点 N/A
符号 GHS07
GHS07
信号词 Warning

Stable preformed chiral palladium catalysts for the one-pot asymmetric reductive amination of ketones.

Org. Lett. 11 , 265-268, (2009)

The application of air stable preformed [(R)-BINAP]PdBr2, [(S)-BINAP]PdBr2, [(R)-Tol-BINAP]PdBr2, and [(S,S)-CHIRAPHOS]PdBr2 complexes in the one-pot asymmetric reductive amination of various carbonyl compounds, leading to chiral amines in very good yields wi...