Palladium, [1,1'-(1R)-[1,1'-binaphthalene]-2,2'-diylbis[1,1-diphenylphosphine-κP]]dibromo-, (SP-4-2) structure
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Common Name | Palladium, [1,1'-(1R)-[1,1'-binaphthalene]-2,2'-diylbis[1,1-diphenylphosphine-κP]]dibromo-, (SP-4-2) | ||
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| CAS Number | 923987-15-9 | Molecular Weight | 888.90000 | |
| Density | N/A | Boiling Point | N/A | |
| Molecular Formula | C44H32Br2P2Pd | Melting Point | N/A | |
| MSDS | Chinese USA | Flash Point | N/A | |
| Symbol |
GHS07 |
Signal Word | Warning | |
| Name | Palladium, [1,1'-(1R)-[1,1'-binaphthalene]-2,2'-diylbis[1,1-diphenylphosphine-κP]]dibromo-, (SP-4-2) |
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| Molecular Formula | C44H32Br2P2Pd |
|---|---|
| Molecular Weight | 888.90000 |
| Exact Mass | 885.93800 |
| PSA | 27.18000 |
| LogP | 10.86760 |
| Symbol |
GHS07 |
|---|---|
| Signal Word | Warning |
| Hazard Statements | H302 + H312 + H332-H315-H319-H335 |
| Precautionary Statements | P261-P280-P305 + P351 + P338 |
| RIDADR | NONH for all modes of transport |
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Stable preformed chiral palladium catalysts for the one-pot asymmetric reductive amination of ketones.
Org. Lett. 11 , 265-268, (2009) The application of air stable preformed [(R)-BINAP]PdBr2, [(S)-BINAP]PdBr2, [(R)-Tol-BINAP]PdBr2, and [(S,S)-CHIRAPHOS]PdBr2 complexes in the one-pot asymmetric reductive amination of various carbonyl... |