Methyl 2-chloroacetoacetate
Methyl 2-chloroacetoacetate structure
|
Common Name | Methyl 2-chloroacetoacetate | ||
|---|---|---|---|---|
| CAS Number | 4755-81-1 | Molecular Weight | 150.56000 | |
| Density | 1.236 g/mL at 25 °C(lit.) | Boiling Point | 137 °C(lit.) | |
| Molecular Formula | C5H7ClO3 | Melting Point | −33-−32.7 °C(lit.) | |
| MSDS | Chinese USA | Flash Point | 161 °F | |
| Symbol |
GHS07 |
Signal Word | Warning | |
|
Chemoselective arylamidine cyclizations: mild formation of 2-arylimidazole-4-carboxylic acids.
Org. Lett. 7(17) , 3801-3, (2005) A versatile, one-pot synthesis of 2-arylimidazole-4-carboxylic acids from arylamidines and methyl-2-chloroacetoacetate is described. The transformation is chemoselective, and reaction conditions are mild. Moreover, the flexibility of the strategy offers rapid... |
|
|
'One-flask'synthesis to 3, 5-disubstituted 1, 2, 4-triazoles from aldehydes with hydrazonoyl hydrochlorides via 1, 3-dipolar cycloaddition. Tseng W-C, et al.
Tetrahedron 67(29) , 5339-45, (2011)
|
Journals:
More...