2-氯乙酰乙酸甲酯
2-氯乙酰乙酸甲酯结构式
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常用名 | 2-氯乙酰乙酸甲酯 | 英文名 | Methyl 2-chloroacetoacetate |
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| CAS号 | 4755-81-1 | 分子量 | 150.56000 | |
| 密度 | 1.236 g/mL at 25 °C(lit.) | 沸点 | 137 °C(lit.) | |
| 分子式 | C5H7ClO3 | 熔点 | −33-−32.7 °C(lit.) | |
| MSDS | 中文版 美版 | 闪点 | 161 °F | |
| 符号 |
GHS07 |
信号词 | Warning |
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Chemoselective arylamidine cyclizations: mild formation of 2-arylimidazole-4-carboxylic acids.
Org. Lett. 7(17) , 3801-3, (2005) A versatile, one-pot synthesis of 2-arylimidazole-4-carboxylic acids from arylamidines and methyl-2-chloroacetoacetate is described. The transformation is chemoselective, and reaction conditions are mild. Moreover, the flexibility of the strategy offers rapid... |
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'One-flask'synthesis to 3, 5-disubstituted 1, 2, 4-triazoles from aldehydes with hydrazonoyl hydrochlorides via 1, 3-dipolar cycloaddition. Tseng W-C, et al.
Tetrahedron 67(29) , 5339-45, (2011)
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