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4755-81-1

4755-81-1 structure
4755-81-1 structure

Name Methyl 2-chloroacetoacetate
Synonyms 2-Chloroacetoacetic Acid Methyl Ester
MFCD00008757
Methyl 2-Chloroacetoacetate
methyl 2-chloro-3-oxobutanoate
EINECS 225-286-6
Density 1.236 g/mL at 25 °C(lit.)
Boiling Point 137 °C(lit.)
Melting Point −33-−32.7 °C(lit.)
Molecular Formula C5H7ClO3
Molecular Weight 150.56000
Flash Point 161 °F
Exact Mass 150.00800
PSA 43.37000
LogP 0.35580
Index of Refraction n20/D 1.446(lit.)
Storage condition 2~8°C
Water Solubility 50 g/L (20 ºC)
Symbol GHS07
GHS07
Signal Word Warning
Hazard Statements H302 + H312 + H332-H315-H319-H335
Precautionary Statements P261-P280-P305 + P351 + P338
Personal Protective Equipment Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter
Hazard Codes Xn: Harmful;
Risk Phrases R22;R36/37/38
Safety Phrases S26-S27-S28-S36/37/39-S37/39
RIDADR UN 2810 6.1/PG 3
WGK Germany 3
Packaging Group III
Hazard Class 8
HS Code 29183000

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4755-81-1 structure

4755-81-1

Literature: Li, Ze; Khaliq, Mansoora; Zhou, Zhigang; Post, Carol Beth; Kuhn, Richard J.; Cushman, Mark Journal of Medicinal Chemistry, 2008 , vol. 51, # 15 p. 4660 - 4671

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4755-81-1 structure

4755-81-1

Literature: Chen, Zizhan; Zhou, Bin; Cai, Huihua; Zhu, Wei; Zou, Xinzhuo Green Chemistry, 2009 , vol. 11, # 2 p. 275 - 278

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4755-81-1 structure

4755-81-1

Literature: Villeras,J. Journal of Organometallic Chemistry, 1972 , vol. 34, p. 209 - 219
HS Code 2918300090
Summary 2918300090 other carboxylic acids with aldehyde or ketone function but without other oxygen function, their anhydrides, halides, peroxides, peroxyacids and their derivatives。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:6.5%。General tariff:30.0%