偶氮基二羧酸双(2,2,2-三氯乙酯)
偶氮基二羧酸双(2,2,2-三氯乙酯)结构式
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常用名 | 偶氮基二羧酸双(2,2,2-三氯乙酯) | 英文名 | Bis(2,2,2-trichloroethyl)Azodicarboxylate |
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| CAS号 | 38857-88-4 | 分子量 | 380.82500 | |
| 密度 | 1.78g/cm3 | 沸点 | 380.7ºC at 760 mmHg | |
| 分子式 | C6H4Cl6N2O4 | 熔点 | 109-111ºC(lit.) | |
| MSDS | 中文版 美版 | 闪点 | 184.1ºC | |
| 符号 |
GHS07 |
信号词 | Warning |
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Catalytic and enantioselective aza-ene and hetero-Diels-Alder reactions of alkenes and dienes with azodicarboxylates.
Org. Biomol. Chem. 3(12) , 2344-9, (2005) Lewis acids such as Cu(OTf)(2), Zn(OTf)(2), Yb(OTf)(3) and Nd(OTf)(3) catalyze the aza-ene reaction of alkenes with azodicarboxylates, giving the allylic amination adducts. The use of bis(2,2,2-trichloroethyl)azodicarboxylate as the amination reagent and Cu(O... |
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Stereoselective formation of carbon-carbon bonds via SN2-displacement: synthesis of substituted cycloalkyl[b]indoles.
J. Org. Chem. 70(21) , 8385-94, (2005) A general asymmetric synthesis of substituted cycloalkyl[b]indoles has been accomplished. The key features of this approach are (1) the utilization of a Japp-Klingemann condensation/Fischer cyclization to prepare cycloalkyl[b]indolones, (2) the asymmetric bor... |
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A convenient synthesis of N-acetyllactosamine derivatives from lactal.
Carbohydr. Res. 247 , 159-64, (1993) In a thermal inverse-type hetero-Diels-Alder reaction of O-silyl-protected lactal 1 and bis(2,2,2-trichloroethyl) azodicarboxylate (2), the dihydrooxadiazine derivative 3 was obtained in a very high yield; transesterification with benzyl alcohol furnished the... |
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N. Boudreault, Y. Leblanc
Organic Synth. 74 , 241, (1997)
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R.D. Little et al.
J. Am. Chem. Soc. 101 , 7129, (1979)
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M. Kaname et al.
Tetrahedron Lett. 40 , 7993 , (1999)
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Y. Leblanc, B.J. Fitzsimmons
Tetrahedron Lett. 30 , 2889, (1989)
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Organic Synth. 61 , 17, (1983)
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Para-directed amination of electron-rich arenes with bis (2, 2, 2-trichloroethyl) azodicarboxylate. Leblanc Y and Boudreault N.
J. Org. Chem. 60(13) , 4268-71, (1995)
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