2-溴乙烯基三甲基硅烷
2-溴乙烯基三甲基硅烷结构式
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常用名 | 2-溴乙烯基三甲基硅烷 | 英文名 | 2-(Bromovinyl)Trimethylsilane |
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| CAS号 | 41309-43-7 | 分子量 | 179.13000 | |
| 密度 | 1.167 g/mL at 25 °C(lit.) | 沸点 | 50-51 °C52 mm Hg(lit.) | |
| 分子式 | C5H11BrSi | 熔点 | N/A | |
| MSDS | 中文版 美版 | 闪点 | 85 °F | |
| 符号 |
GHS02, GHS07 |
信号词 | Warning |
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Palladium-Catalyzed Cross-Coupling Syntheses of Benzotriazolyl Enynes and a General Route to Enynyl Ketones and Alkynyl Ketones.
J. Org. Chem. 62(23) , 8201-8204, (1997) A new general route to conjugated enynyl ketones was developed based on a two-step procedure. First, palladium-catalyzed cross-coupling reactions of 1-(benzotriazol-1-yl)propargyl ethyl ether (3) and vinyl triflates or vinyl bromides afforded the key intermed... |
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Ligand effects on Negishi couplings of alkenyl halides.
Org. Lett. 13(15) , 3818-21, (2011) Negishi couplings at olefinic centers do not always occur with the anticipated maintenance of stereochemistry. The source of erosion has been traced to the ligand, and a modified method has been developed that solves the stereochemical issue and significantly... |
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Spiro [2.4] hepta-1, 4, 6-triene Billups WE, et al.
J. Am. Chem. Soc. 116(14) , 6463, (1994)
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