2-(Bromovinyl)Trimethylsilane
2-(Bromovinyl)Trimethylsilane structure
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Common Name | 2-(Bromovinyl)Trimethylsilane | ||
|---|---|---|---|---|
| CAS Number | 41309-43-7 | Molecular Weight | 179.13000 | |
| Density | 1.167 g/mL at 25 °C(lit.) | Boiling Point | 50-51 °C52 mm Hg(lit.) | |
| Molecular Formula | C5H11BrSi | Melting Point | N/A | |
| MSDS | Chinese USA | Flash Point | 85 °F | |
| Symbol |
GHS02, GHS07 |
Signal Word | Warning | |
| Name | 2-(Bromovinyl)Trimethylsilane |
|---|---|
| Synonym | More Synonyms |
| Density | 1.167 g/mL at 25 °C(lit.) |
|---|---|
| Boiling Point | 50-51 °C52 mm Hg(lit.) |
| Molecular Formula | C5H11BrSi |
| Molecular Weight | 179.13000 |
| Flash Point | 85 °F |
| Exact Mass | 177.98100 |
| LogP | 2.77240 |
| Index of Refraction | n20/D 1.466(lit.) |
| Storage condition | 2-8°C |
| Symbol |
GHS02, GHS07 |
|---|---|
| Signal Word | Warning |
| Hazard Statements | H226-H315-H319-H335 |
| Precautionary Statements | P261-P305 + P351 + P338 |
| Personal Protective Equipment | Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter |
| Hazard Codes | Xi |
| Risk Phrases | 10-36/37/38 |
| Safety Phrases | 26 |
| RIDADR | UN 1993 3/PG 3 |
| WGK Germany | 3 |
| HS Code | 2931900090 |
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~74%
2-(Bromovinyl)T... CAS#:41309-43-7 |
| Literature: Lang, Yunhui; Souza, Fabio E. S.; Xu, Xinshe; Taylor, Nicholas J.; Assoud, Abdeljalil; Rodrigo, Russell Journal of Organic Chemistry, 2009 , vol. 74, # 15 p. 5429 - 5439 |
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~%
2-(Bromovinyl)T... CAS#:41309-43-7 |
| Literature: Pillot,J.P. et al. Synthetic Communications, 1979 , vol. 9, p. 395 - 406 |
|
~%
2-(Bromovinyl)T... CAS#:41309-43-7 |
| Literature: Pillot,J.P. et al. Synthetic Communications, 1979 , vol. 9, p. 395 - 406 |
|
~%
2-(Bromovinyl)T... CAS#:41309-43-7 |
| Literature: Pillot,J.P. et al. Synthetic Communications, 1979 , vol. 9, p. 395 - 406 |
|
~%
2-(Bromovinyl)T... CAS#:41309-43-7 |
| Literature: Mironow et al. Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1959 , p. 1954,1958;engl.Ausg.S.1864,1868 Full Text Show Details Mironow; Petrow Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1958 , p. 787; engl. Ausg. S. 767 |
| Precursor 6 | |
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| DownStream 10 | |
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CAS#:81256-02-2| HS Code | 2931900090 |
|---|---|
| Summary | 2931900090. other organo-inorganic compounds. VAT:17.0%. Tax rebate rate:13.0%. Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward). MFN tariff:6.5%. General tariff:30.0% |
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Palladium-Catalyzed Cross-Coupling Syntheses of Benzotriazolyl Enynes and a General Route to Enynyl Ketones and Alkynyl Ketones.
J. Org. Chem. 62(23) , 8201-8204, (1997) A new general route to conjugated enynyl ketones was developed based on a two-step procedure. First, palladium-catalyzed cross-coupling reactions of 1-(benzotriazol-1-yl)propargyl ethyl ether (3) and ... |
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Ligand effects on Negishi couplings of alkenyl halides.
Org. Lett. 13(15) , 3818-21, (2011) Negishi couplings at olefinic centers do not always occur with the anticipated maintenance of stereochemistry. The source of erosion has been traced to the ligand, and a modified method has been devel... |
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Spiro [2.4] hepta-1, 4, 6-triene Billups WE, et al.
J. Am. Chem. Soc. 116(14) , 6463, (1994)
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| β-(trimethylsilyl)vinyl bromide |
| MFCD00040824 |
| [(E)-2-BROMOVINYL](TRIMETHYL)SILANE |
| 2-BROMOVINYLTRIMETHYLSILANE |
| 2-(BROMOVINYL)TRIMETHYLSILANE |
| (2-BROMOVINYL)TRIMETHYLSILANE |