(±)-6,6'-二溴-1,1'-联-2-萘酚
(±)-6,6'-二溴-1,1'-联-2-萘酚结构式
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常用名 | (±)-6,6'-二溴-1,1'-联-2-萘酚 | 英文名 | 6,6'-Dibromo-1,1'-binaphthalene-2,2'-diol |
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| CAS号 | 13185-00-7 | 分子量 | 444.116 | |
| 密度 | 1.8±0.1 g/cm3 | 沸点 | 546.2±45.0 °C at 760 mmHg | |
| 分子式 | C20H12Br2O2 | 熔点 | 195-199ºC(lit.) | |
| MSDS | 中文版 | 闪点 | 284.1±28.7 °C | |
| 符号 |
GHS07 |
信号词 | Warning |
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Conformational sensitivity of chiroptical spectroscopic methods: 6,6'-dibromo-1,1'-bi-2-naphthol.
J. Phys. Chem. A 113(18) , 5423-31, (2009) The experimental vibrational circular dichroism (VCD), electronic circular dichroism (ECD), and optical rotatory dispersion (ORD) spectra for both enantiomers of 6,6'-dibromo-1,1'-bi-2-naphthol have been measured. The corresponding quantum chemical prediction... |
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Novel binuclear chiral zirconium catalysts used in enantioselective strecker reactions.
Chirality 12(5-6) , 540-3, (2000) A novel binuclear chiral zirconium catalyst was successfully used in enantioselective Strecker reactions. The catalyst was readily prepared from zirconium t-butoxide (Zr(OtBu)4), (R)-6,6'-dibromo-1, 1'-bi-2-naphthol ((R)-6-Br-BINOL), and (R)-3,3'-dibromo-1, 1... |
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Diastereoselective and enantioselective glyoxylate-ene reaction catalyzed by new class of binaphthol-derived titanium complex. Terada M, et al.
Tetrahedron Lett. 35(36) , 6693-6696, (1996)
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