6,6'-Dibromo-1,1'-binaphthalene-2,2'-diol
6,6'-Dibromo-1,1'-binaphthalene-2,2'-diol structure
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Common Name | 6,6'-Dibromo-1,1'-binaphthalene-2,2'-diol | ||
|---|---|---|---|---|
| CAS Number | 13185-00-7 | Molecular Weight | 444.116 | |
| Density | 1.8±0.1 g/cm3 | Boiling Point | 546.2±45.0 °C at 760 mmHg | |
| Molecular Formula | C20H12Br2O2 | Melting Point | 195-199ºC(lit.) | |
| MSDS | Chinese | Flash Point | 284.1±28.7 °C | |
| Symbol |
GHS07 |
Signal Word | Warning | |
| Name | (s)-(+)-6,6'-dibromo-1,1'-bi-2-naphthol |
|---|---|
| Synonym | More Synonyms |
| Density | 1.8±0.1 g/cm3 |
|---|---|
| Boiling Point | 546.2±45.0 °C at 760 mmHg |
| Melting Point | 195-199ºC(lit.) |
| Molecular Formula | C20H12Br2O2 |
| Molecular Weight | 444.116 |
| Flash Point | 284.1±28.7 °C |
| Exact Mass | 441.920380 |
| PSA | 40.46000 |
| LogP | 5.91 |
| Vapour Pressure | 0.0±1.5 mmHg at 25°C |
| Index of Refraction | 1.779 |
| InChIKey | OORIFUHRGQKYEV-UHFFFAOYSA-N |
| SMILES | Oc1ccc2cc(Br)ccc2c1-c1c(O)ccc2cc(Br)ccc12 |
| Symbol |
GHS07 |
|---|---|
| Signal Word | Warning |
| Hazard Statements | H315-H319-H335 |
| Precautionary Statements | P261-P305 + P351 + P338 |
| Personal Protective Equipment | dust mask type N95 (US);Eyeshields;Gloves |
| Hazard Codes | Xi |
| Risk Phrases | R36/37/38 |
| Safety Phrases | 26-36 |
| RIDADR | NONH for all modes of transport |
| WGK Germany | 3 |
|
~99%
6,6'-Dibromo-1,... CAS#:13185-00-7 |
| Literature: Bunzen, Jens; Bruhn, Torsten; Bringmann, Gerhard; Luetzen, Arne Journal of the American Chemical Society, 2009 , vol. 131, p. 3621 - 3630 |
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6,6'-Dibromo-1,... CAS#:13185-00-7 |
| Literature: Synlett, , # 10 p. 1433 - 1436 |
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6,6'-Dibromo-1,... CAS#:13185-00-7 |
| Literature: Chemistry Letters, , # 4 p. 352 - 353 |
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6,6'-Dibromo-1,... CAS#:13185-00-7 |
| Literature: Organic Letters, , vol. 4, # 15 p. 2529 - 2532 |
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6,6'-Dibromo-1,... CAS#:13185-00-7 |
| Literature: Tetrahedron Letters, , vol. 36, # 44 p. 7991 - 7994 |
| Precursor 2 | |
|---|---|
| DownStream 0 | |
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Conformational sensitivity of chiroptical spectroscopic methods: 6,6'-dibromo-1,1'-bi-2-naphthol.
J. Phys. Chem. A 113(18) , 5423-31, (2009) The experimental vibrational circular dichroism (VCD), electronic circular dichroism (ECD), and optical rotatory dispersion (ORD) spectra for both enantiomers of 6,6'-dibromo-1,1'-bi-2-naphthol have b... |
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Novel binuclear chiral zirconium catalysts used in enantioselective strecker reactions.
Chirality 12(5-6) , 540-3, (2000) A novel binuclear chiral zirconium catalyst was successfully used in enantioselective Strecker reactions. The catalyst was readily prepared from zirconium t-butoxide (Zr(OtBu)4), (R)-6,6'-dibromo-1, 1... |
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Diastereoselective and enantioselective glyoxylate-ene reaction catalyzed by new class of binaphthol-derived titanium complex. Terada M, et al.
Tetrahedron Lett. 35(36) , 6693-6696, (1996)
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| (±)-6,6'-Dibromo-2,2'-dihydroxy-1,1'-binaphthyl |
| 6-bromo-1-(6-bromo-2-hydroxynaphthalen-1-yl)naphthalen-2-ol |
| MFCD00798290 |
| 6,6'-Dibromo-1,1'-binaphthalene-2,2'-diol |
| [1,1'-Binaphthalene]-2,2'-diol, 6,6'-dibromo- |
| )-6,6'-Dibromo-1,1'-bi-2-naphthol |
| (+/-)-6,6'-DibroMo-1,1'-bi-2-naphthol |
| 6,6′-Dibromo-1,1′-bi-2-naphthol |