6,6'-Dibromo-1,1'-binaphthalene-2,2'-diol
6,6'-Dibromo-1,1'-binaphthalene-2,2'-diol structure
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Common Name | 6,6'-Dibromo-1,1'-binaphthalene-2,2'-diol | ||
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| CAS Number | 13185-00-7 | Molecular Weight | 444.116 | |
| Density | 1.8±0.1 g/cm3 | Boiling Point | 546.2±45.0 °C at 760 mmHg | |
| Molecular Formula | C20H12Br2O2 | Melting Point | 195-199ºC(lit.) | |
| MSDS | Chinese | Flash Point | 284.1±28.7 °C | |
| Symbol |
GHS07 |
Signal Word | Warning | |
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Conformational sensitivity of chiroptical spectroscopic methods: 6,6'-dibromo-1,1'-bi-2-naphthol.
J. Phys. Chem. A 113(18) , 5423-31, (2009) The experimental vibrational circular dichroism (VCD), electronic circular dichroism (ECD), and optical rotatory dispersion (ORD) spectra for both enantiomers of 6,6'-dibromo-1,1'-bi-2-naphthol have been measured. The corresponding quantum chemical prediction... |
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Novel binuclear chiral zirconium catalysts used in enantioselective strecker reactions.
Chirality 12(5-6) , 540-3, (2000) A novel binuclear chiral zirconium catalyst was successfully used in enantioselective Strecker reactions. The catalyst was readily prepared from zirconium t-butoxide (Zr(OtBu)4), (R)-6,6'-dibromo-1, 1'-bi-2-naphthol ((R)-6-Br-BINOL), and (R)-3,3'-dibromo-1, 1... |
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Diastereoselective and enantioselective glyoxylate-ene reaction catalyzed by new class of binaphthol-derived titanium complex. Terada M, et al.
Tetrahedron Lett. 35(36) , 6693-6696, (1996)
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