[1,3-双(2,6-二-3-戊基苯基)咪唑-2-亚基](3-氯吡啶基)二氯化钯(II)
二氯化钯(II)结构式](https://image.chemsrc.com/caspic/346/1158652-41-5.png)
[1,3-双(2,6-二-3-戊基苯基)咪唑-2-亚基](3-氯吡啶基)二氯化钯(II)结构式
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常用名 | [1,3-双(2,6-二-3-戊基苯基)咪唑-2-亚基](3-氯吡啶基)二氯化钯(II) | 英文名 | Pd-PEPPSI-IPent catalyst |
|---|---|---|---|---|
| CAS号 | 1158652-41-5 | 分子量 | 793.688 | |
| 密度 | N/A | 沸点 | N/A | |
| 分子式 | C40H58Cl3N3Pd | 熔点 | N/A | |
| MSDS | 中文版 美版 | 闪点 | N/A | |
| 符号 |
GHS07 |
信号词 | Warning |
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Pd-PEPPSI-IPent: an active, sterically demanding cross-coupling catalyst and its application in the synthesis of tetra-ortho-substituted biaryls.
Angew. Chem. Int. Ed. Engl. 48 , 2383, (2009) Incredible Bulk: A series of N-heterocyclic carbene catalysts (see picture) were prepared and evaluated in the Suzuki-Miyaura reaction. A variety of sterically encumbered tetra-ortho-substituted biaryl products were formed from unreactive aryl chlorides using... |
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Pd-PEPPSI-IPent: low-temperature negishi cross-coupling for the preparation of highly functionalized, tetra-ortho-substituted biaryls.
Angew. Chem. Int. Ed. Engl. 49 , 2014, (2010)
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An efficient low-temperature Stille-Migita cross-coupling reaction for heteroaromatic compounds by Pd-PEPPSI-IPent.
Chemistry 16 , 4279, (2010) The reactivity of Pd-PEPPSI (Pyridine, Enhanced, Precatalyst, Preparation, Stabilization, and Initiation) precatalysts in the Stille-Migita cross-coupling reaction between heteroaryl stannanes and aryl or heteroaryl halides was evaluated. In general, Pd-PEPPS... |
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The development of bulky palladium NHC complexes for the most-challenging cross-coupling reactions.
Angew. Chem. Int. Ed. Engl. 51 , 3314, (2012) Palladium-catalyzed cross-coupling reactions enable organic chemists to form C-C bonds in targeted positions and under mild conditions. Although phosphine ligands have been intensively researched, in the search for even better cross-coupling catalysts attenti... |