Pd-PEPPSI-IPent catalyst
Pd-PEPPSI-IPent catalyst structure
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Common Name | Pd-PEPPSI-IPent catalyst | ||
|---|---|---|---|---|
| CAS Number | 1158652-41-5 | Molecular Weight | 793.688 | |
| Density | N/A | Boiling Point | N/A | |
| Molecular Formula | C40H58Cl3N3Pd | Melting Point | N/A | |
| MSDS | Chinese USA | Flash Point | N/A | |
| Symbol |
GHS07 |
Signal Word | Warning | |
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Pd-PEPPSI-IPent: an active, sterically demanding cross-coupling catalyst and its application in the synthesis of tetra-ortho-substituted biaryls.
Angew. Chem. Int. Ed. Engl. 48 , 2383, (2009) Incredible Bulk: A series of N-heterocyclic carbene catalysts (see picture) were prepared and evaluated in the Suzuki-Miyaura reaction. A variety of sterically encumbered tetra-ortho-substituted biaryl products were formed from unreactive aryl chlorides using... |
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Pd-PEPPSI-IPent: low-temperature negishi cross-coupling for the preparation of highly functionalized, tetra-ortho-substituted biaryls.
Angew. Chem. Int. Ed. Engl. 49 , 2014, (2010)
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An efficient low-temperature Stille-Migita cross-coupling reaction for heteroaromatic compounds by Pd-PEPPSI-IPent.
Chemistry 16 , 4279, (2010) The reactivity of Pd-PEPPSI (Pyridine, Enhanced, Precatalyst, Preparation, Stabilization, and Initiation) precatalysts in the Stille-Migita cross-coupling reaction between heteroaryl stannanes and aryl or heteroaryl halides was evaluated. In general, Pd-PEPPS... |
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The development of bulky palladium NHC complexes for the most-challenging cross-coupling reactions.
Angew. Chem. Int. Ed. Engl. 51 , 3314, (2012) Palladium-catalyzed cross-coupling reactions enable organic chemists to form C-C bonds in targeted positions and under mild conditions. Although phosphine ligands have been intensively researched, in the search for even better cross-coupling catalysts attenti... |