Pd-PEPPSI-IPent catalyst
Pd-PEPPSI-IPent catalyst structure
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Common Name | Pd-PEPPSI-IPent catalyst | ||
|---|---|---|---|---|
| CAS Number | 1158652-41-5 | Molecular Weight | 793.688 | |
| Density | N/A | Boiling Point | N/A | |
| Molecular Formula | C40H58Cl3N3Pd | Melting Point | N/A | |
| MSDS | Chinese USA | Flash Point | N/A | |
| Symbol |
GHS07 |
Signal Word | Warning | |
| Name | 1,3-bis[2,6-bis(1-ethylpropyl)phenyl]-2H-imidazole;3-chloropyridine;dichloropalladium |
|---|---|
| Synonym | More Synonyms |
| Molecular Formula | C40H58Cl3N3Pd |
|---|---|
| Molecular Weight | 793.688 |
| Exact Mass | 791.273132 |
| InChIKey | VYJIWPKHKYUFCP-UHFFFAOYSA-L |
| SMILES | CCC(CC)c1cccc(C(CC)CC)c1N1C=CN(c2c(C(CC)CC)cccc2C(CC)CC)C1.Clc1cccnc1.[Cl-].[Cl-].[Pd+2] |
| Storage condition | -20°C |
| Symbol |
GHS07 |
|---|---|
| Signal Word | Warning |
| Hazard Statements | H302-H312-H332 |
| Precautionary Statements | P280 |
| RIDADR | NONH for all modes of transport |
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Pd-PEPPSI-IPent: an active, sterically demanding cross-coupling catalyst and its application in the synthesis of tetra-ortho-substituted biaryls.
Angew. Chem. Int. Ed. Engl. 48 , 2383, (2009) Incredible Bulk: A series of N-heterocyclic carbene catalysts (see picture) were prepared and evaluated in the Suzuki-Miyaura reaction. A variety of sterically encumbered tetra-ortho-substituted biary... |
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Pd-PEPPSI-IPent: low-temperature negishi cross-coupling for the preparation of highly functionalized, tetra-ortho-substituted biaryls.
Angew. Chem. Int. Ed. Engl. 49 , 2014, (2010)
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An efficient low-temperature Stille-Migita cross-coupling reaction for heteroaromatic compounds by Pd-PEPPSI-IPent.
Chemistry 16 , 4279, (2010) The reactivity of Pd-PEPPSI (Pyridine, Enhanced, Precatalyst, Preparation, Stabilization, and Initiation) precatalysts in the Stille-Migita cross-coupling reaction between heteroaryl stannanes and ary... |
| MFCD18253025 |