N-苯基羟胺
N-苯基羟胺结构式
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常用名 | N-苯基羟胺 | 英文名 | N-Phenylhydroxylamine |
|---|---|---|---|---|
| CAS号 | 100-65-2 | 分子量 | 109.12600 | |
| 密度 | 1.214g/cm3 | 沸点 | 215.8ºC at 760mmHg | |
| 分子式 | C6H7NO | 熔点 | 83 - 84ºC | |
| MSDS | 中文版 美版 | 闪点 | 120.2ºC | |
| 符号 |
GHS06 |
信号词 | Danger |
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In situ infrared monitoring of the solid/liquid catalyst interface during the three-phase hydrogenation of nitrobenzene over nanosized Au on TiO2.
Phys. Chem. Chem. Phys. 13(27) , 12463-71, (2011) The three-phase hydrogenation of nitrobenzene catalysed by nanosized gold over titania was investigated in a slurry. Simultaneous in situ ATR-FTIR monitoring of the liquid phase and at the solid/liquid catalyst interface identified the species adsorbed on the... |
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Genotoxic activities of aniline and its metabolites and their relationship to the carcinogenicity of aniline in the spleen of rats.
Crit. Rev. Toxicol. 35(10) , 783-835, (2005) Aniline (in the form of its hydrochloride) has been shown to induce a rather rare spectrum of tumors in the spleen of Fischer 344 rats. The dose levels necessary for this carcinogenic activity were in a range where also massive effects on the blood and non-ne... |
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Biotransformation of hydroxylaminobenzene and aminophenol by Pseudomonas putida 2NP8 cells grown in the presence of 3-nitrophenol.
Appl. Environ. Microbiol. 66(6) , 2336-42, (2000) Biotransformation products of hydroxylaminobenzene and aminophenol produced by 3-nitrophenol-grown cells of Pseudomonas putida 2NP8, a strain grown on 2- and 3-nitrophenol, were characterized. Ammonia, 2-aminophenol, 4-aminophenol, 4-benzoquinone, N-acetyl-4-... |
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Superoxide dismutase-mediated reversible conversion of 3-hydroxyamino-1-methyl-5H-pyrido[4,3-b]indole, the N-hydroxy derivative of Trp-P-2, into its nitroso derivative.
Carcinogenesis 9(11) , 2003-8, (1988) Aerobic oxidation of 3-hydroxyamino-1-methyl-5H-pyrido-[4,3-b]indole [Trp-P-2(NHOH)] in neutral aqueous solution was greatly accelerated by copper-zinc superoxide dismutase (SOD). The major product in this SOD-mediated reaction was identified as 3-nitroso-1-m... |
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[Phenoxenium ions: generations and reactions].
Yakugaku Zasshi 114(8) , 565-76, (1994) The acid-catalyzed reaction of N-acyl- and N-sulfonylhydroxylamines with benzene proceeded smoothly to give C-C products; 2- and 4-hydroxybiphenyls. The reaction and the thermolysis of N-aryloxypyridinium salts involve common intermediates. The results of pro... |
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Thrombelastographic characterization of coagulation/fibrinolysis in horses: role of carboxyheme and metheme states.
Blood Coagul. Fibrinolysis 24(3) , 273-8, (2013) Carboxyheme and metheme states modulate hemostasis in humans and other species. Further, carbon monoxide and/or nitric oxide production increase in inflammatory disorders involving the gastrointestinal tract, with associated hypercoagulability or hypocoagulab... |
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Redox-based thrombelastographic method to detect carboxyhemefibrinogen-mediated hypercoagulability.
Blood Coagul. Fibrinolysis 22(8) , 657-61, (2011) Cigarette smoking is associated with plasmatic hypercoagulability, and carbon monoxide has been demonstrated to enhance coagulation by binding to a fibrinogen-bound heme. Our objective was to design and test a redox-based method to detect carboxyhemefibrinoge... |
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N,O-diacyl-4-benzoyl-N-phenylhydroxylamines as photoinduced DNA cleaving agents.
Bioorg. Med. Chem. Lett. 20(18) , 5414-7, (2010) Photoinduced homolytic fission of nitrogen-oxygen bond in N,O-diacyl-4-benzoyl-N-phenylhydroxylamines using 310 nm UV light for 10 min produced acylaminyl and acyloxy radicals, which resulted in single strand cleavage of DNA at pH 7.0. Further the DNA cleavin... |
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Carbon monoxide and nitric oxide modulate α₂-antiplasmin and plasmin activity: role of heme.
Blood Coagul. Fibrinolysis 22(8) , 712-9, (2011) Cigarette smoke and carbon monoxide (CO) released from tricarbonyldichlororuthenium (II) dimer (CORM-2) attenuate fibrinolysis. The purpose of the present study was to determine whether CO diminished fibrinolysis by enhancement of α₂-antiplasmin via a putativ... |
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Hemolytic drugs aniline and dapsone induce iron release in erythrocytes and increase the free iron pool in spleen and liver.
Toxicol. Lett. 110 , 57-66, (1999) Incubation of rat erythrocytes with the hydroxylated metabolites of aniline and dapsone (4-4'-diaminodiphenylsulfone), phenylhydroxylamine and dapsone hydroxylamine, respectively, induced marked release of iron and methemoglobin formation. On the contrary, no... |