1,1'-Bis(diphenylphosphino)ferrocene-palladium(II)dichloridedichloromethanecomplex

1,1'-Bis(diphenylphosphino)ferrocene-palladium(II)dichloridedichloromethanecomplex Structure
1,1'-Bis(diphenylphosphino)ferrocene-palladium(II)dichloridedichloromethanecomplex structure
Common Name 1,1'-Bis(diphenylphosphino)ferrocene-palladium(II)dichloridedichloromethanecomplex
CAS Number 95464-05-4 Molecular Weight 816.64
Density 1 g/cm3 Boiling Point N/A
Molecular Formula C35H30Cl4FeP2Pd Melting Point 275-280ºC(lit.)
MSDS Chinese USA Flash Point N/A
Symbol GHS07 GHS08
GHS07, GHS08
Signal Word Warning

Pd-catalyzed carbonylative lactamization: a novel synthetic approach to FR900482.

Org. Lett. 6 , 1745, (2004)

An asymmetric synthesis of the benzazocine core of FR900482 has been achieved in 15 steps from 3,5-dinitro-p-toluic acid. Key features of the synthesis include an enantioselective N-methylephedrine-mediated zinc acetylide addition to a highly enolizable aryla...

Tetrahedron 62 , 2006, (2006)

Tetrahedron 62 , 9002, (2006)

Total synthesis of TMC-95A and -B via a new reaction leading to Z-enamides. Some preliminary findings as to SAR.

J. Am. Chem. Soc. 126 , 6347, (2004)

A full account of the total syntheses of proteasome inhibitors TMC-95A and -B is provided. A key feature of the syntheses involved installation of a cis-propenylamide moiety by a thermal rearrangement of an alpha-silylallyl amide. The scope and mechanism of t...