[1,1'-双(二苯基膦)二茂铁]二氯化钯二氯甲烷络合物
![[1,1'-双(二苯基膦)二茂铁]二氯化钯二氯甲烷络合物结构式](https://image.chemsrc.com/caspic/147/95464-05-4.png)
[1,1'-双(二苯基膦)二茂铁]二氯化钯二氯甲烷络合物结构式
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常用名 | [1,1'-双(二苯基膦)二茂铁]二氯化钯二氯甲烷络合物 | 英文名 | 1,1'-Bis(diphenylphosphino)ferrocene-palladium(II)dichloridedichloromethanecomplex |
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| CAS号 | 95464-05-4 | 分子量 | 816.64 | |
| 密度 | 1 g/cm3 | 沸点 | N/A | |
| 分子式 | C35H30Cl4FeP2Pd | 熔点 | 275-280ºC(lit.) | |
| MSDS | 中文版 美版 | 闪点 | N/A | |
| 符号 |
GHS07, GHS08 |
信号词 | Warning |
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Pd-catalyzed carbonylative lactamization: a novel synthetic approach to FR900482.
Org. Lett. 6 , 1745, (2004) An asymmetric synthesis of the benzazocine core of FR900482 has been achieved in 15 steps from 3,5-dinitro-p-toluic acid. Key features of the synthesis include an enantioselective N-methylephedrine-mediated zinc acetylide addition to a highly enolizable aryla... |
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Tetrahedron 62 , 2006, (2006)
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Tetrahedron 62 , 9002, (2006)
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Total synthesis of TMC-95A and -B via a new reaction leading to Z-enamides. Some preliminary findings as to SAR.
J. Am. Chem. Soc. 126 , 6347, (2004) A full account of the total syntheses of proteasome inhibitors TMC-95A and -B is provided. A key feature of the syntheses involved installation of a cis-propenylamide moiety by a thermal rearrangement of an alpha-silylallyl amide. The scope and mechanism of t... |