(S)-(+)-Benzyl glycidyl ether

(S)-(+)-Benzyl glycidyl ether Structure
(S)-(+)-Benzyl glycidyl ether structure
Common Name (S)-(+)-Benzyl glycidyl ether
CAS Number 16495-13-9 Molecular Weight 164.201
Density 1.1±0.1 g/cm3 Boiling Point 252.7±15.0 °C at 760 mmHg
Molecular Formula C10H12O2 Melting Point N/A
MSDS Chinese USA Flash Point 100.9±19.9 °C
Symbol GHS07
GHS07
Signal Word Warning

Bioresolution of benzyl glycidyl ether using whole cells of Bacillus alcalophilus.

J. Basic Microbiol. 52(4) , 383-9, (2012)

The incubation of whole Bacillus alcalophilus cells grown on a mineral supplemented medium (MSM) containing 1% (w/v) sucrose as carbon source, 1.2% (w/v) tryptone as nitrogen source at pH 6.5 and temperature 30 °C in 24 h kinetically resolved benzyl glycidyl ...

Metal-mediated cyclization of aryl and benzyl glycidyl ethers: a complete scenario.

J. Am. Chem. Soc. 130(50) , 16838-9, (2008)

Enantiomerically pure aryl and benzyl glycidyl ethers undergo stereospecific cyclizations leading to 3-chromanols or to tetrahydrobenzo[c]oxepin-4-ols under mild conditions in the presence of a catalytic amount of FeBr3/3AgOTf. The same processes are also med...

Enantioselective total synthesis of (+)-gigantecin: exploiting the asymmetric glycolate aldol reaction.

J. Am. Chem. Soc. 126(40) , 12790-1, (2004)

The enantioselective synthesis of the potent, selective, cytotoxic, annonaceous acetogenin, (+)-gigantecin, has been completed. An asymmetric glycolate aldol serves to establish the stereocenters at C13,14 and at C21,22. A Carreira asymmetric acetylide additi...

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