Ethyl bromofluoroacetate
Ethyl bromofluoroacetate structure
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Common Name | Ethyl bromofluoroacetate | ||
|---|---|---|---|---|
| CAS Number | 401-55-8 | Molecular Weight | 184.99200 | |
| Density | 1.565 g/mL at 25 °C(lit.) | Boiling Point | 154 °C(lit.) | |
| Molecular Formula | C4H6BrFO2 | Melting Point | N/A | |
| MSDS | Chinese USA | Flash Point | 159 °F | |
| Symbol |
GHS07 |
Signal Word | Warning | |
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Visible-light-mediated fluoroalkylation of isocyanides with ethyl bromofluoroacetates: unified synthesis of mono- and difluoromethylated phenanthridine derivatives.
Org. Lett. 16(11) , 2938-41, (2014) A practical and unified strategy has been described for the preparation of mono- and difluoromethylated phenanthridine derivatives using a visible-light-promoted alkylation and decarboxylation sequence from biphenyl isocyanides with ethyl bromofluoroacetate (... |
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A straightforward and highly diastereoselective access to functionalized monofluorinated cyclopropanes via a Michael initiated ring closure reaction.
Org. Lett. 15(21) , 5598-601, (2013) The synthesis of highly functionalized monofluorinated cyclopropanes based on a Michael Initiated Ring Closure (MIRC) reaction has been developed. The addition of quaternary ammonium salts derived from ethyl bromofluoroacetate on a panel of electron deficient... |
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Catalyzed Reformatsky reactions with ethyl bromofluoroacetate for the synthesis of alpha-fluoro-beta-hydroxy acids.
J. Org. Chem. 67(1) , 72-8, (2002) The presence of catalytic amounts of CeCl(3) improves yields and simplifies procedure in the Reformatsky reactions of ethyl bromofluoroacetate with aldehydes and ketones to generate diastereomeric mixtures of alpha-fluoro-beta-hydroxy esters, some of which ca... |
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