溴氟乙酸乙酯
溴氟乙酸乙酯结构式
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常用名 | 溴氟乙酸乙酯 | 英文名 | Ethyl bromofluoroacetate |
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| CAS号 | 401-55-8 | 分子量 | 184.99200 | |
| 密度 | 1.565 g/mL at 25 °C(lit.) | 沸点 | 154 °C(lit.) | |
| 分子式 | C4H6BrFO2 | 熔点 | N/A | |
| MSDS | 中文版 美版 | 闪点 | 159 °F | |
| 符号 |
GHS07 |
信号词 | Warning |
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Visible-light-mediated fluoroalkylation of isocyanides with ethyl bromofluoroacetates: unified synthesis of mono- and difluoromethylated phenanthridine derivatives.
Org. Lett. 16(11) , 2938-41, (2014) A practical and unified strategy has been described for the preparation of mono- and difluoromethylated phenanthridine derivatives using a visible-light-promoted alkylation and decarboxylation sequence from biphenyl isocyanides with ethyl bromofluoroacetate (... |
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A straightforward and highly diastereoselective access to functionalized monofluorinated cyclopropanes via a Michael initiated ring closure reaction.
Org. Lett. 15(21) , 5598-601, (2013) The synthesis of highly functionalized monofluorinated cyclopropanes based on a Michael Initiated Ring Closure (MIRC) reaction has been developed. The addition of quaternary ammonium salts derived from ethyl bromofluoroacetate on a panel of electron deficient... |
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Catalyzed Reformatsky reactions with ethyl bromofluoroacetate for the synthesis of alpha-fluoro-beta-hydroxy acids.
J. Org. Chem. 67(1) , 72-8, (2002) The presence of catalytic amounts of CeCl(3) improves yields and simplifies procedure in the Reformatsky reactions of ethyl bromofluoroacetate with aldehydes and ketones to generate diastereomeric mixtures of alpha-fluoro-beta-hydroxy esters, some of which ca... |
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Synthesis of (E)-and (Z)-fluoro-olefin analogues of potent dipeptidyl peptidase IV inhibitors. Van der Veken P, et al.
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