lithium triflate
lithium triflate structure
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Common Name | lithium triflate | ||
|---|---|---|---|---|
| CAS Number | 33454-82-9 | Molecular Weight | 156.01 | |
| Density | 1,9 g/cm3 | Boiling Point | 162ºC at 760mmHg | |
| Molecular Formula | CF3LiO3S | Melting Point | >300 °C(lit.) | |
| MSDS | Chinese USA | Flash Point | N/A | |
| Symbol |
GHS07 |
Signal Word | Warning | |
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Effect of three trifluoromethanesulfonate ionic liquids on the activity, stability and conformation of laccase.
Int. J. Biol. Macromol. 56 , 62-8, (2013) The activity, stability and conformation of laccase were first investigated in an aqueous solution of ionic liquids 1-butyl-3-methylimidazolium trifluoromethanesulfonate ([Bmim]TfO), 1-butyl-1-methylpyrrolidinium trifluoromethanesulfonate ([Bmpyr]TfO) or tetr... |
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Ultrathin Nanotube/Nanowire Electrodes by Spin-Spray Layer-by-Layer Assembly: A Concept for Transparent Energy Storage.
ACS Nano 9 , 10005-17, (2015) Fully integrated transparent devices require versatile architectures for energy storage, yet typical battery electrodes are thick (20-100 μm) and composed of optically absorbent materials. Reducing the length scale of active materials, assembling them with a ... |
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In(III)/PhCO2H binary acid catalyzed tandem [2 + 2] cycloaddition and Nazarov reaction between alkynes and acetals.
Org. Lett. 15(17) , 4496-9, (2013) A facile tandem [2 + 2] cycloaddition and Nazarov reaction has been developed. The combination of In(OTf)3 and benzoic acid was found to synergistically promote the coupling of alkynes and acetals to form 2,3-disubstituted indanones in excellent yield and dia... |
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The synthesis of 3,5,6,7-tetrasubstituted isoxazolo[4,5-b]pyridines and an evaluation of their in vitro antiproliferative activity.
Adv. Clin. Exp. Med. 21(5) , 563-71, (2012) Derivatives of isoxazolopyridines exhibit diverse biological activity. One method of synthesizing isoxazolo[4,5-b]pyridines is Friedlander condensation.To establish the conditions necessary for conventional and microwave synthesis of new 3,5,6,7-tetrasubstitu... |
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Michael addition/pericyclization/rearrangement--a multicomponent strategy for the synthesis of substituted resorcinols.
Org. Biomol. Chem. 10(31) , 6388-94, (2012) The combination of methyl 3,7-dioxo-2-diazo-4-octenoate from the zinc triflate catalyzed Mukaiyama-Michael reaction of methyl 3-tert-butylsilyloxy-2-diazobutenoate and 4-methoxy-3-buten-2-one with Michael acceptors (methyl vinyl ketone, N-phenylmaleimide, β-n... |
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One-pot protocol to functionalized benzopyrrolizidine catalyzed successively by Rh2(OAc)4 and Cu(OTf)2: a transition metal-Lewis acid catalysis relay.
Org. Lett. 17(1) , 66-9, (2015) 4-N-allylarylpropylamino-1-sulfonyl triazoles are converted to structurally unique benzopyrrolizidinyl sulfonamides in a one-pot operation. Intramolecular capture of rhodium carbene with arylamino nitrogen gives rise to the formation of an ammonium ylide imme... |
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Hybrid Lithium-Sulfur Batteries with a Solid Electrolyte Membrane and Lithium Polysulfide Catholyte.
ACS Appl. Mater. Interfaces 7 , 16625-31, (2015) Lithium-sulfur (Li-S) batteries are receiving great attention as the most promising next-generation power source with significantly high charge-storage capacity. However, the implementation of Li-S batteries is hampered by a critical challenge because of the ... |
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Chemoselective synthesis of substituted pyrazoles through AgOTf-catalyzed cascade propargylic substitution-cyclization-aromatization.
Org. Biomol. Chem. 11(2) , 294-8, (2013) A cascade AgOTf-catalyzed chemoselective approach to 3,5/1,3-disubstitued pyrazoles from propargylic alcohols and para-tolylsulfonohydrazide has been developed. Good chemoselectivity is observed depending on the different substituents in the alkyne moiety of ... |
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Total synthesis of (-)-cinatrin C1 based on an In(OTf)3-catalyzed Conia-Ene reaction.
J. Org. Chem. 78(8) , 3847-57, (2013) The stereocontrolled total synthesis of (-)-cinatrin C1, a phospholipase A2 inhibitor, has been accomplished. The key feature includes the stereoselective construction of the highly substituted tetrahydrofuran core by In(OTf)3-catalyzed Conia-ene reaction of ... |
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In situ formation of β-glycosyl imidinium triflate from participating thioglycosyl donors: elaboration to disarmed-armed iterative glycosylation.
Chem. Commun. (Camb.) 48(88) , 10910-2, (2012) β-Glycosyl imidinium triflate is generated from participating thioglycoside donors for disarmed-armed iterative glycosylations and one-pot oligosaccharide synthesis. |