Chemical Communications 2012-11-14

In situ formation of β-glycosyl imidinium triflate from participating thioglycosyl donors: elaboration to disarmed-armed iterative glycosylation.

Yu Hsien Lin, Bhaswati Ghosh, Kwok-Kong Tony Mong

Index: Chem. Commun. (Camb.) 48(88) , 10910-2, (2012)

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Abstract

β-Glycosyl imidinium triflate is generated from participating thioglycoside donors for disarmed-armed iterative glycosylations and one-pot oligosaccharide synthesis.

Structure	Name/CAS No.	Molecular Formula	Articles
	lithium triflate CAS:33454-82-9	CF₃LiO₃S
	Zinc trifluoromethanesulfonate CAS:54010-75-2	C₂F₆O₆S₂Zn
	Trifluoromethanesulfonic acid CAS:1493-13-6	CHF₃O₃S
	Barium bis(trifluoromethanesulfonate) CAS:2794-60-7	C₂BaF₆O₆S₂

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In situ formation of β-glycosyl imidinium triflate from participating thioglycosyl donors: elaboration to disarmed-armed iterative glycosylation.

Abstract

Related Compounds