phenylallylchloro-[1,3-bis(diisopropylphenyl)imidazole-2-ylidene]palladium(ii)

phenylallylchloro-[1,3-bis(diisopropylphenyl)imidazole-2-ylidene]palladium(ii) Structure
phenylallylchloro-[1,3-bis(diisopropylphenyl)imidazole-2-ylidene]palladium(ii) structure
Common Name phenylallylchloro-[1,3-bis(diisopropylphenyl)imidazole-2-ylidene]palladium(ii)
CAS Number 884879-23-6 Molecular Weight 647.62900
Density N/A Boiling Point N/A
Molecular Formula C36H45ClN2Pd Melting Point N/A
MSDS Chinese USA Flash Point N/A
Symbol GHS07
GHS07
Signal Word Warning

Room-temperature Suzuki-Miyaura couplings in water facilitated by nonionic amphiphiles.

Org. Lett. 10 , 1333, (2008)

Use of a dilute aqueous solution containing a nonionic amphiphile allows efficient Suzuki-Miyaura cross-couplings of arylboronic acids with a wide array of aryl halides and pseudohalides, including sterically hindered and lipophilic substrates, in most cases ...

Modified (NHC)Pd(allyl)Cl (NHC = N-heterocyclic carbene) complexes for room-temperature Suzuki-Miyaura and Buchwald-Hartwig reactions.

J. Am. Chem. Soc. 128 , 4101, (2006)

A series of (NHC)Pd(R-allyl)Cl complexes [NHC: IPr = N,N'-bis(2,6-diisopropylphenyl)imidazol-2-ylidene, SIPr = N,N'-bis(2,6-diisopropylphenyl)-4,5-dihydroimidazol-2-ylidene; R = H, Me, gem-Me2, Ph] have been synthesized and fully characterized. When compared ...

Rapid room temperature Buchwald-Hartwig and Suzuki-Miyaura couplings of heteroaromatic compounds employing low catalyst loadings.

Chemistry 12 , 5142, (2006)

The use of second-generation [(NHC)Pd(R-allyl)Cl] complexes for Suzuki-Miyaura and Buchwald-Hartwig cross-coupling reactions involving heteroaromatic halides at room temperature is reported. The first examples of room temperature Suzuki-Miyaura cross-coupling...