phenylallylchloro-[1,3-bis(diisopropylphenyl)imidazole-2-ylidene]palladium(ii)
![phenylallylchloro-[1,3-bis(diisopropylphenyl)imidazole-2-ylidene]palladium(ii) Structure](https://image.chemsrc.com/caspic/165/884879-23-6.png)
phenylallylchloro-[1,3-bis(diisopropylphenyl)imidazole-2-ylidene]palladium(ii) structure
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Common Name | phenylallylchloro-[1,3-bis(diisopropylphenyl)imidazole-2-ylidene]palladium(ii) | ||
|---|---|---|---|---|
| CAS Number | 884879-23-6 | Molecular Weight | 647.62900 | |
| Density | N/A | Boiling Point | N/A | |
| Molecular Formula | C36H45ClN2Pd | Melting Point | N/A | |
| MSDS | Chinese USA | Flash Point | N/A | |
| Symbol |
GHS07 |
Signal Word | Warning | |
| Name | [1,3-Bis(2,6-diisopropylphenyl)imidazol-2-ylidene]chloro[3-phenylallyl]palladium(II) 95% |
|---|---|
| Synonym | More Synonyms |
| Molecular Formula | C36H45ClN2Pd |
|---|---|
| Molecular Weight | 647.62900 |
| Exact Mass | 646.23100 |
| PSA | 9.86000 |
| LogP | 10.84780 |
| Storage condition | -20°C |
| Symbol |
GHS07 |
|---|---|
| Signal Word | Warning |
| Hazard Statements | H302-H312-H315-H319-H332 |
| Precautionary Statements | P280-P305 + P351 + P338 |
| Personal Protective Equipment | dust mask type N95 (US);Eyeshields;Gloves |
| Hazard Codes | Xn |
| Risk Phrases | 20/21/22-36/38 |
| Safety Phrases | 22-24/25-26-36/37 |
| RIDADR | NONH for all modes of transport |
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Room-temperature Suzuki-Miyaura couplings in water facilitated by nonionic amphiphiles.
Org. Lett. 10 , 1333, (2008) Use of a dilute aqueous solution containing a nonionic amphiphile allows efficient Suzuki-Miyaura cross-couplings of arylboronic acids with a wide array of aryl halides and pseudohalides, including st... |
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Modified (NHC)Pd(allyl)Cl (NHC = N-heterocyclic carbene) complexes for room-temperature Suzuki-Miyaura and Buchwald-Hartwig reactions.
J. Am. Chem. Soc. 128 , 4101, (2006) A series of (NHC)Pd(R-allyl)Cl complexes [NHC: IPr = N,N'-bis(2,6-diisopropylphenyl)imidazol-2-ylidene, SIPr = N,N'-bis(2,6-diisopropylphenyl)-4,5-dihydroimidazol-2-ylidene; R = H, Me, gem-Me2, Ph] ha... |
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Rapid room temperature Buchwald-Hartwig and Suzuki-Miyaura couplings of heteroaromatic compounds employing low catalyst loadings.
Chemistry 12 , 5142, (2006) The use of second-generation [(NHC)Pd(R-allyl)Cl] complexes for Suzuki-Miyaura and Buchwald-Hartwig cross-coupling reactions involving heteroaromatic halides at room temperature is reported. The first... |
| Chloro[(1,2,3-n)-3-phenyl-2-propenyl][1,3-bis(2,6-di-i-propylphenyl)imidazol-2-ylidene]palladium(II),min. |
| PHENYLALLYLCHLORO-[1,3-BIS(DIISOPROPYLPHENYL)IMIDAZOLE-2-YLIDENE]PALLADIUM(II) |
| Chloro[(1,2,3-)-3-phenyl-2-propenyl][1,3-bis(2,6-di-i-propylphenyl)iMidazol-2-ylidene]palladiuM(II),Min. |