Mesityl oxide
Mesityl oxide structure
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Common Name | Mesityl oxide | ||
|---|---|---|---|---|
| CAS Number | 141-79-7 | Molecular Weight | 98.143 | |
| Density | 0.8±0.1 g/cm3 | Boiling Point | 132.7±9.0 °C at 760 mmHg | |
| Molecular Formula | C6H10O | Melting Point | −53 °C(lit.) | |
| MSDS | Chinese USA | Flash Point | 30.6±0.0 °C | |
| Symbol |
GHS02, GHS06 |
Signal Word | Danger | |
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Synthesis of modified homo-N-nucleosides from the reactions of mesityl nitrile oxide with 9-allylpurines and their influence on lipid peroxidation and thrombin inhibition
Bioorg. Med. Chem. Lett. 19 , 6433-6, (2009) The synthesized compounds act as lipid peroxidation inhibitors and potent thrombin inhibitors. |
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The strongest isolable acid.
Angew. Chem. Int. Ed. Engl. 43(40) , 5352-5, (2004)
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Preparation and evaluation of an imidazole-coated capillary column for the electrophoretic separation of aromatic acids.
J. Chromatogr. A. 897(1-2) , 383-92, (2000) An imidazole-coated capillary column for electrophoresis has been prepared by means of organosilanization. With mesityl oxide as neutral marker, the results indicated that the electroosmotic flow of the bonded phase displays a dramatic difference in pH depend... |
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Refined Synthesis of 2,3,4,5-Tetrahydro-1,3,3-trimethyldipyrrin, a Deceptively Simple Precursor to Hydroporphyrins.
Org. Process Res. Dev. 9(5) , 651-659, (2005) 2,3,4,5-Tetrahydro-1,3,3-trimethyldipyrrin (1) is a crucial building block in the rational synthesis of chlorins and oxochlorins. The prior 5-step synthesis of 1 from pyrrole-2-carboxaldehyde (2) employed relatively simple and well-known reactions yet suffere... |
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Two-dimensional capillary electrophoresis using tangentially connected capillaries.
J. Chromatogr. A. 1154(1-2) , 454-9, (2007) A novel type of fused silica capillary system is described where channels with circular cross-sections are tangentially in contact with each other and connected through a small opening at the contact area. Since the channels are not crossing each other in the... |
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Optimization of resolution in capillary zone electrophoresis: combined effect of applied voltage and buffer concentration.
J. Chromatogr. A. 588(1-2) , 315-20, (1991) Expressions are formulated for the prediction of solute migration time and resolution as a function applied voltage and buffer concentration in capillary zone electrophoresis. The resolution equation assumes that solute diffusion is the only operative zone-br... |
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On the mechanism of the Skraup-Doebner-Von Miller quinoline synthesis.
J. Org. Chem. 71(4) , 1668-76, (2006) The mechanism of the formation of substituted quinolines from anilines and alpha,beta-unsaturated ketones has been studied by the use of 13C-labeled ketones in cross-over experiments. In the reaction of doubly labeled 13C(2,4) mesityl oxide, a 100% scrambling... |
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Medium-throughput pKa screening pharmaceuticals by pressure-assisted capillary electrophoresis.
Electrophoresis 22(6) , 1112-8, (2001) A fast screening method for the determination of the dissociation constants (pKa) of acidic, basic, and multivalent compounds was developed by using pressure-assisted capillary electrophoresis (PACE). External air pressure was applied to shorten the analysis ... |
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Analysis of a model reaction system containing cysteine and (E)-2-methyl-2-butenal, (E)-2-hexenal, or mesityl oxide.
J. Agric. Food Chem. 51(24) , 7146-55, (2003) Cysteine conjugates, resulting from the addition of cysteine to alpha,beta-unsaturated carbonyl compounds, are important precursors of odorant sulfur compounds in food flavors. The aim of this work was to better understand this chemistry in the light of the u... |
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Determination of effective mobilities of EOF markers in BGE containing sulfated β-cyclodextrin by a two-detector method.
Electrophoresis 34(5) , 768-76, (2013) A neutral marker of the EOF can gain a nonzero effective mobility because of its possible interaction with a charged complexing agent, such as a chiral selector in CE. We determined effective mobilities of four compounds often used as EOF markers (dimethyl su... |