Ethyl methoxyacetate

Ethyl methoxyacetate Structure
Ethyl methoxyacetate structure
Common Name Ethyl methoxyacetate
CAS Number 3938-96-3 Molecular Weight 118.131
Density 1.0±0.1 g/cm3 Boiling Point 144.1±13.0 °C at 760 mmHg
Molecular Formula C5H10O3 Melting Point N/A
MSDS Chinese USA Flash Point 46.1±0.0 °C
Symbol GHS02
GHS02
Signal Word Warning

Molecular basis for the enhanced lipase-catalyzed N-acylation of 1-phenylethanamine with methoxyacetate.

ChemBioChem. 7(11) , 1745-9, (2006)

One of the commercial methods for preparing enantiopure amines is lipase-catalyzed kinetic resolution, although lipases catalyze aminolysis with only low activity. Interestingly, in 1997 Balkenhohl et al. used ethyl methoxyacetate instead of ethyl butyrate as...

Hydration structure of poly(2-methoxyethyl acrylate): comparison with a 2-methoxyethyl acetate model monomer.

J. Biomater. Sci. Polym. Ed. 21(14) , 1925-35, (2010)

We have previously reported the hydration structure of a poly(2-methoxyethyl acrylate) (PMEA) antithrombogenic material. In the present study, the hydration structure of a 2-methoxyethyl acetate (MEAc) model monomer for PMEA was explored by means of attenuate...

Reagents for (ir)reversible enzymatic acylations.

Org. Biomol. Chem. 1(14) , 2405-15, (2003)

Commonly, hydrolase-catalysed reactions are used for kinetic resolutions of alcohols, amines and acids. Only a few applications in total syntheses have been described. Most of these examples are for the synthesis of amides and peptides. Here, the synthesis of...

Enzymatic enantiomeric resolution of phenylethylamines structurally related to amphetamine.

Org. Biomol. Chem. 9(23) , 8171-7, (2011)

Both enantiomers of several phenylethylamines, structurally related to amphetamine, have been prepared in good yields and excellent enantiomeric purity by enzymatic kinetic resolution using CAL-B and ethyl methoxyacetate as the acyl donor. In the case of the ...

Application of automated matrix-assisted laser desorption/ionization time-of-flight mass spectrometry for the measurement of enzyme activities.

Rapid Commun. Mass Spectrom. 15(15) , 1327-33, (2001)

Sample preparation methods and data acquisition protocols were optimized for the application of matrix-assisted laser desorption/ionization time-of-flight mass spectrometry (MALDI-TOFMS) to high-throughput quantitative analysis of low molecular mass substrate...

Aneuploidy-inducing chemicals in yeast evaluated by the micronucleus test.

Mutat. Res. 174(1) , 11-3, (1986)

Chinese hamsters were exposed to acetone, methyl ethyl ketone, ethyl acetate and 2-methoxy ethyl acetate, known to be strong inducers of aneuploidy in the yeast Saccharomyces cerevisiae. All solvents yielded negative results in the micronucleus test, whereas ...

Urinary 2-methoxy acetic acid accumulation in response to 2-methoxy ethanol exposure.

Arch. Environ. Health 56(1) , 20-5, (2001)

Urinary 2-methoxy acetic acid reportedly has a long half-life (77.1 hr) in humans. The authors studied urinary 2-methoxy acetic acid in a group of 18 workers exposed to 2-methoxy ethanol from Monday to Saturday following a 7-d cease in production. The weekly ...

Aneuploidy in Drosophila, II. Further validation of the FIX and ZESTE genetic test systems employing female Drosophila melanogaster.

Mutat. Res. 259(2) , 147-63, (1991)

Two sensitive genetic systems for the detection of germline aneuploidy employing Drosophila melanogaster females were described in the first paper of this series (Zimmering et al., submitted to Mutation Research). Designated FIX and ZESTE, these systems permi...

Improved sensitivity for high resolution in situ hybridization using resin extraction of methyl methacrylate embedded material.

Biotech. Histochem. 74(1) , 40-8, (1999)

An in situ hybridization procedure resulting in both high resolution and sensitivity was established by using the removable methyl methacrylate resin, Technovit 9100. Young bicellular pollen of tobacco (Nicotiana tabacum L. SR-1) was embedded in Technovit 910...

Aneuploidy in Drosophila. III: Aneuploidogens inhibit in vitro assembly of taxol-purified Drosophila microtubules.

Environ. Mol. Mutagen. 16(4) , 217-24, (1990)

The in vitro effects of aneuploidogens on taxol-purified microtubules from whole Drosophila melanogaster and mouse brain were studied by a spectrophotometric assay and electron microscopy. Colchicine, acetonitrile, propionitrile, acrylonitrile, dimethylsulfox...