9-Borabicyclo[3.3.1]nonane
![9-Borabicyclo[3.3.1]nonane Structure](https://image.chemsrc.com/caspic/244/280-64-8.png)
9-Borabicyclo[3.3.1]nonane structure
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Common Name | 9-Borabicyclo[3.3.1]nonane | ||
|---|---|---|---|---|
| CAS Number | 280-64-8 | Molecular Weight | 122.016 | |
| Density | 0.894 g/mL at 25 °C | Boiling Point | 179.3±23.0 °C at 760 mmHg | |
| Molecular Formula | C8H15B | Melting Point | 150 - 152ºC | |
| MSDS | USA | Flash Point | 62.3±22.6 °C | |
| Symbol |
GHS02, GHS07, GHS08 |
Signal Word | Danger | |
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Spectroscopic and microscopic investigation of gold nanoparticle formation: ligand and temperature effects on rate and particle size.
J. Am. Chem. Soc. 133(21) , 8179-90, (2011) We report a spectroscopic and microscopic investigation of the synthesis of gold nanoparticles (AuNPs) with average sizes of less than 5 nm. The slow reduction and AuNP formation processes that occur by using 9-borabicyclo[3.3.1]nonane (9-BBN) as a reducing a... |
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Synthesis of aryl/alkyl building blocks for dendrimer and hyperbranched polymer synthesis.
Org. Lett. 6 , 667-669, (2004) Several useful aryl/alkyl building blocks for dendrimer and hyperbranched polymer synthesis were prepared by Suzuki-Miyaura cross-coupling reactions and iododesilylation reactions. The iododesilylations were carried out with iodine monochloride (ICl) in methy... |
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Multicomponent Mannich reactions with boron enolates derived from diazo esters and 9-BBN.
Org. Lett. 13 , 2510, (2011) Diazo esters, arylboranes, and carbamoyl imines undergo a 3-component Mannich condensation reaction. Catalyzed by Cu(II) salts, the reaction affords the corresponding isocyanate Mannich product: one that can be easily trapped in situ by other nucleophiles. Th... |
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PS-COD and PS-9-BBN: polymer-supported reagents for solution-phase parallel synthesis.
Org. Lett. 7(5) , 831-3, (2005) 1,5-Cyclooctadiene was deprotonated under LICKOR conditions and reacted with Merrifield resin to afford an immobilized cyclooctadiene in high yield. This polymer is effective as a halogen scavenger, while hydroboration leads to a supported 9-BBN analogue. The... |
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Solid-phase synthesis in the twenty-first century.
Mini Rev. Med. Chem. 6(1) , 3-10, (2006) Solid-phase synthesis is a powerful tool for achieving high-throughput chemistry. This review discusses recent diverse examples from my group: the solid-phase synthesis of unsymmetrical guanidines, polymer-supported versions of cyclooctadiene and 9-BBN, a tri... |
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Chem. Lett. 33 , 396-397, (2004)
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Chemtracts 13 , 219-222, (2000)
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Org. Process Res. Dev. 10 , 1076, (2006)
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