adamantanone
adamantanone structure
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Common Name | adamantanone | ||
|---|---|---|---|---|
| CAS Number | 700-58-3 | Molecular Weight | 150.218 | |
| Density | 1.1±0.1 g/cm3 | Boiling Point | 246.7±8.0 °C at 760 mmHg | |
| Molecular Formula | C10H14O | Melting Point | 256-258 °C (subl.)(lit.) | |
| MSDS | Chinese USA | Flash Point | 95.7±10.7 °C | |
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Effect of adamantanone derivative possessing anti-HIV properties on the redox processes in the cytochrome P-450 system.
Dokl. Biochem. Biophys. 378 , 210-3, (2001)
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Conformational relaxation in hemoproteins: the cytochrome P-450cam case.
Biochemistry 39(46) , 14219-31, (2000) Photodissociation of (CO)P-450(cam)(substrate) complexes was found to trigger a conformational relaxation process that interferes with ligand rebinding at temperatures as low as 140 K even though the protein conformational substates (CS(1)) remain frozen. To ... |
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The structural basis for substrate-induced changes in redox potential and spin equilibrium in cytochrome P-450CAM.
Biochemistry 28(2) , 917-22, (1989) The crystal structures of cytochrome P-450CAM complexed with the alternative substrates norcamphor and adamantanone have been refined at 2.0-A resolution and compared with the native, camphor-bound form of the enzyme. Norcamphor lacks the 8-, 9-, and 10-methy... |
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(+/-)-1-(Adamantan-2-yl)-2-propanamine and other amines derived from 2-adamantanone.
Farmaco. Sci. 35(5) , 430-40, (1980) The synthesis of (+/-)-1-(adamantan-2-yl)-2-propanamine (VI), its N,N-dimethyl derivative (VII) and other amines (VIII), (IX) and (X), starting from 2-adamantanone, is described. Some of these amines showed antiparkinson activity in mice. |
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Synthesis of a silene from 1,1-dilithiosilole and 2-adamantanone.
J. Am. Chem. Soc. 126(17) , 5336-7, (2004) Reaction of 1,1-dilithio-1-sila-2,3,4,5-tetraphenylsilole with 2-adamantanone produces a 5-silafulvene. This represents a new method for synthesis of silenes, leading to the first example of a silapentafulvene. |
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Piperidine dispiro-1,2,4-trioxane analogues.
Bioorg. Med. Chem. Lett. 18(21) , 5804-8, (2008) Dispiro N-Boc-protected 1,2,4-trioxane 2 was synthesised via Mo(acac)(2) catalysed perhydrolysis of N-Boc spirooxirane followed by condensation of the resulting beta-hydroperoxy alcohol 10 with 2-adamantanone. N-Boc 1,2,4-trioxane 2 was converted to the amine... |
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Enolates in 3-D: an experimental and computational study of deprotonated 2-adamantanone.
J. Org. Chem. 75(12) , 4274-9, (2010) Deprotonation of 2-adamantanone (1) in the gas phase affords the corresponding beta-enolate anion. This ion was independently prepared by the fluoride-induced desilylation of 4-trimethylsilyl-2-adamantanone, and its reactivity and thermodynamic properties wer... |
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Mechanically induced chemiluminescence from polymers incorporating a 1,2-dioxetane unit in the main chain.
Nature Chemistry 4(7) , 559-62, (2012) Nature uses mechanochemical transduction processes to achieve diverse and vital functions, such as hearing, cellular adhesion and gating of ion channels. One fascinating example of biological mechanotransduction is the emission of light on mechanical stimulat... |
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Tuning the conversion of cyclohexane into cyclohexanol/one by molecular dioxygen, protons and reducing agents at a single non-porphyrinic iron centre and chemical versatility of the tris(2-pyridylmethyl)amine TPAFe(II)Cl2 complex in mild oxidation chemistry.
Dalton Trans. 40(1) , 92-106, (2011) We report that the oxygen sensitivity of some Fe(II) complexes with tripodal ligands can be used, with benefit, in the oxidation of cyclohexane under mild conditions. Depending on the solvent, two very different reaction pathways are involved, which share the... |
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Effect of membrane lipid perturbers on the temperature dependence of repair of sublethal and potentially lethal radiation damage.
Int. J. Radiat. Biol. Relat. Stud. Phys. Chem. Med. 39(2) , 195-205, (1981) The repair of sublethal radiation damage (SLD) in Chinese hamster (V79) cells was investigated as a function of temperature in the presence and absence of the membrane lipid perturbers, butylated hydroxytoluene (BHT) or adamantanone, which decrease the viscos... |