(4-Chlorophenyl)boronic acid
(4-Chlorophenyl)boronic acid structure
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Common Name | (4-Chlorophenyl)boronic acid | ||
|---|---|---|---|---|
| CAS Number | 1679-18-1 | Molecular Weight | 156.375 | |
| Density | 1.3±0.1 g/cm3 | Boiling Point | 295.4±42.0 °C at 760 mmHg | |
| Molecular Formula | C6H6BClO2 | Melting Point | 284-289 °C(lit.) | |
| MSDS | Chinese USA | Flash Point | 132.4±27.9 °C | |
| Symbol |
GHS07 |
Signal Word | Warning | |
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Cationic Pd(II)-catalyzed highly enantioselective arylative cyclization of alkyne-tethered enals or enones initiated by carbopalladation of alkynes with arylboronic acids.
Org. Lett. 7th ed., 14 , 1756-1759, (2012) Cationic Pd(II)-catalyzed enantioselective arylative cyclization of alkyne-tethered enals or enones initiated by carbopalladation of alkynes was developed without the necessity of a redox system. |
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Ruthenium(0)-catalyzed sp3 C-H bond arylation of benzylic amines using arylboronates.
Org. Lett. 7th ed., 14 , 1930-1933, (2012) A Ru-catalyzed direct arylation of benzylic sp(3) carbons of acyclic amines with arylboronates is reported. This highly regioselective and efficient transformation can be performed with various combinations of N-(2-pyridyl) substituted benzylamines and arylbo... |
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Tandem-type Pd(II)-catalyzed oxidative Heck reaction/intramolecular C-H amidation sequence: a novel route to 4-aryl-2-quinolinones.
Chem. Commun. (Camb.) 36th ed., 48 , 4332-4334, (2012) A novel catalytic method for synthesizing 4-aryl-2-quinolinones is reported. The process involves two mechanistically independent, sequential Pd(II)-catalyzed reactions--the oxidative Heck reaction and the intramolecular C-H amidation--both of which smoothly ... |
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Pd-catalyzed direct arylation of phenylpyrazole: Synthesis of fipronil derivatives with aryl boronic acids promoted by a stoichiometric amount of NIS Zhang, X-H.; Han, J-S.; Zhong, P.
J. Fluor. Chem. 137 , 44-49, (2012)
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Ligand-free copper-catalyzed coupling of nitroarenes with arylboronic acids Zhang, J.; et al.
Green Chem. 4th ed., 14 , 912-916, (2012)
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Regioselective Arylation and Alkynylation of 2,3-Dibromo-1H-inden-1-one by Suzuki-Miyaura and Sonogashira Cross-Coupling Reactions Khera, R. A.; et al.
Helv. Chim. Acta 3rd ed., 95 , 469-482, (2012)
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Suzuki-Miyaura cross-coupling reaction of aryl bromides catalyzed by palladium(II) pyridoxal hydrazone complexes Pandiarajan, D.; Ramesh, R.
J. Organomet. Chem. 708-709 , 18-24, (2012)
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Palladium(II) thiocarboxamide complexes: synthesis, characterisation and application to catalytic Suzuki coupling reactions.
Dalton Trans. 17th ed., 41 , 5351-5361, (2012) A simple route to synthesise palladium(II) complexes from the reaction of N-substituted pyridine-2-thiocarboxamide ligands and PdCl(2)(PPh(3))(2) has been developed. The new complexes are very soluble in common solvents and have been fully characterised (elem... |
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Synlett , 127, (2007)
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Tetrahedron Lett. 48 , 827, (2007)
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