(S)-VAPOL
(S)-VAPOL structure
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Common Name | (S)-VAPOL | ||
|---|---|---|---|---|
| CAS Number | 147702-15-6 | Molecular Weight | 623.566 | |
| Density | 1.287 g/cm3 | Boiling Point | 712.173ºC at 760 mmHg | |
| Molecular Formula | C41H28Cl2O2 | Melting Point | 185-191ºC | |
| MSDS | USA | Flash Point | 298.408ºC | |
| Symbol |
GHS08 |
Signal Word | Warning | |
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New synthesis of vaulted biaryl ligands via the Snieckus phenol synthesis.
Org. Lett. 7 , 367, (2005) [reaction: see text] In an effort to develop a synthesis of the VAPOL ligand that avoids the use of a chromium carbene complex, a route was examined that involved the annulation of a naphthalene carboxamide via the method of Snieckus. The latter derivatives c... |
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Highly enantioselective deracemization of linear and vaulted biaryl ligands.
Org. Lett. 5 , 1813, (2003) [reaction: see text] A copper-mediated deracemization of the vaulted biaryl ligands VANOL and VAPOL can be readily achieved in the presence of (-)-spartiene. The optimal procedure involves the in situ generation of copper(II) and leads to the reproducible for... |
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Bao. J. et al.
J. Am. Chem. Soc. 118 , 3392, (1996)
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