(S)-VAPOL
Modify Date: 2024-01-08 20:42:44
(S)-VAPOL structure
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Common Name | (S)-VAPOL | ||
|---|---|---|---|---|
| CAS Number | 147702-15-6 | Molecular Weight | 623.566 | |
| Density | 1.287 g/cm3 | Boiling Point | 712.173ºC at 760 mmHg | |
| Molecular Formula | C41H28Cl2O2 | Melting Point | 185-191ºC | |
| MSDS | USA | Flash Point | 298.408ºC | |
| Symbol |
GHS08 |
Signal Word | Warning | |
| Name | (3S)-(+)-2,2'-Diphenyl-[3,3'-biphenanthrene]-4,4'-diol dichloromethane adduct (S)-VAPOL |
|---|---|
| Synonym | More Synonyms |
| Density | 1.287 g/cm3 |
|---|---|
| Boiling Point | 712.173ºC at 760 mmHg |
| Melting Point | 185-191ºC |
| Molecular Formula | C41H28Cl2O2 |
| Molecular Weight | 623.566 |
| Flash Point | 298.408ºC |
| Exact Mass | 622.146606 |
| PSA | 40.46000 |
| LogP | 12.13310 |
| Symbol |
GHS08 |
|---|---|
| Signal Word | Warning |
| Hazard Statements | H351 |
| Precautionary Statements | P281 |
| Hazard Codes | Xn |
| Risk Phrases | 37/38-40-41 |
| Safety Phrases | 26-36/37/39-36/37-24/25-23 |
| RIDADR | NONH for all modes of transport |
| Precursor 3 | |
|---|---|
| DownStream 0 | |
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New synthesis of vaulted biaryl ligands via the Snieckus phenol synthesis.
Org. Lett. 7 , 367, (2005) [reaction: see text] In an effort to develop a synthesis of the VAPOL ligand that avoids the use of a chromium carbene complex, a route was examined that involved the annulation of a naphthalene carbo... |
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Highly enantioselective deracemization of linear and vaulted biaryl ligands.
Org. Lett. 5 , 1813, (2003) [reaction: see text] A copper-mediated deracemization of the vaulted biaryl ligands VANOL and VAPOL can be readily achieved in the presence of (-)-spartiene. The optimal procedure involves the in situ... |
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Bao. J. et al.
J. Am. Chem. Soc. 118 , 3392, (1996)
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| [3,3'-Biphenanthrene]-4,4'-diol, 2,2'-diphenyl-, compd. with dichloromethane (1:1) |
| 2,2'-Diphenyl-3,3'-biphenanthrene-4,4'-diol - dichloromethane (1:1) |