UNII:FE7IK35OPN

UNII:FE7IK35OPN Structure
UNII:FE7IK35OPN structure
Common Name UNII:FE7IK35OPN
CAS Number 2269-22-9 Molecular Weight 246.322
Density 1.237 g/mL at 25 °C Boiling Point 40 °C
Molecular Formula C12H27AlO3 Melting Point N/A
MSDS Chinese USA Flash Point 82 °F
Symbol GHS02 GHS06
GHS02, GHS06
Signal Word Danger

The substrate binding cavity of particulate methane monooxygenase from Methylosinus trichosporium OB3b expresses high enantioselectivity for n-butane and n-pentane oxidation to 2-alcohol.

Biotechnol. Lett. 33(11) , 2241-6, (2011)

The particulate methane monooxygenase (pMMO) of Methylosinus trichosporium OB3b oxidized n-butane and n-pentane and mainly produced (R)-2-butanol and (R)-2-pentanol that comprised 78 and 89% of the product, respectively, indicating that the pro-R hydrogen of ...

Thermally induced structural evolution and performance of mesoporous block copolymer-directed alumina perovskite solar cells.

ACS Nano 8(5) , 4730-9, (2014)

Structure control in solution-processed hybrid perovskites is crucial to design and fabricate highly efficient solar cells. Here, we utilize in situ grazing incidence wide-angle X-ray scattering and scanning electron microscopy to investigate the structural e...

Interplay of metalloligand and organic ligand to tune micropores within isostructural mixed-metal organic frameworks (M'MOFs) for their highly selective separation of chiral and achiral small molecules.

J. Am. Chem. Soc. 134(20) , 8703-10, (2012)

Four porous isostructural mixed-metal-organic frameworks (M'MOFs) have been synthesized and structurally characterized. The pores within these M'MOFs are systematically tuned by the interplay of both the metalloligands and organic ligands which have enabled u...

Complex suicide by ethanol intoxication and inhalation of fire fumes in an old lady: interdisciplinary elucidation including post-mortem analysis of congener alcohols.

Forensic Sci. Int. 209(1-3) , e11-5, (2011)

An 88-year-old woman committed suicide by drinking a toxic amount of highly concentrated alcohol and setting two rooms of her flat on fire. As there was not enough oxygen, the fire went out, however. At autopsy, no thermal lesions were found on the body, but ...

Requirement of phospholipase D for ilimaquinone-induced Golgi membrane fragmentation.

J. Biol. Chem. 282(47) , 34085-92, (2007)

Although organelles such as the endoplasmic reticulum and Golgi apparatus are highly compartmentalized, these organelles are interconnected through a network of vesicular trafficking. The marine sponge metabolite ilimaquinone (IQ) is known to induce Golgi mem...

Intermolecular chiral assemblies in R(-) and S(+) 2-butanol detected by microcalorimetry measurements.

Chirality 24(7) , 500-5, (2012)

Supramolecular chiral assemblies of R(-) and S(+) 2-butanol, in their neat form or when dissolved in their nonchiral isomer isobutanol, were evaluated by isothermal titration calorimetry (ITC) ensuing mixing. Dilution of 0.5 M solution of R(-) 2-butanol in is...

Effects of butanol isomers on dipalmitoylphosphatidylcholine bilayer membranes.

Biophys. Chem. 128(1) , 13-8, (2007)

Differential scanning calorimetry and (31)P-NMR were used to study the effects of butanol isomers on the thermotropic phase behavior of dipalmitoylphosphatidylcholine (DPPC) bilayers. The threshold concentration for the onset of interdigitation for each isome...

Analysis of vibrational circular dichroism spectra of (s)-(+)-2-butanol by rotational strengths expressed in local symmetry coordinates.

J. Phys. Chem. A 110(6) , 2122-9, (2006)

The vibrational circular dichroism (VCD) spectra of (S)-(+)-2-butanol have been observed in dilute CS(2) solutions. Two strong VCD bands are assigned mainly to the OH bending modes with the aid of quantum chemical calculations. The calculated VCD spectra corr...

Monosaccharides as internal probes for the determination of the absolute configuration of 2-butanol.

Magn. Reson. Chem. 44(2) , 132-8, (2006)

D-Glucose, D-mannose and L-rhamnose were reacted with a racemic mixture of 2-butanol, and the resulting alpha-glycosides were analyzed by 1H NMR with COSY and NOESY experiments. Conformational analysis of alpha-glycosidic bonds performed with molecular modeli...

Structural studies of five novel bile acid-4-aminopyridine conjugates.

Steroids 77(11) , 1141-51, (2012)

Synthesis and solid-state structural characterization of five bile acid amides of 4-aminopyridine (4-AP) are reported. Systematic crystallization experiments revealed a number of structural modifications and/or solvate/hydrate systems for these conjugates. Pa...