Tetrahydropyran
Tetrahydropyran structure
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Common Name | Tetrahydropyran | ||
|---|---|---|---|---|
| CAS Number | 142-68-7 | Molecular Weight | 86.132 | |
| Density | 0.9±0.1 g/cm3 | Boiling Point | 88.0±0.0 °C at 760 mmHg | |
| Molecular Formula | C5H10O | Melting Point | −45 °C(lit.) | |
| MSDS | Chinese USA | Flash Point | -15.6±0.0 °C | |
| Symbol |
GHS02, GHS07 |
Signal Word | Danger | |
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Structurally and stereochemically diverse tetrahydropyran synthesis through oxidative C-H bond activation.
Angew. Chem. Int. Ed. Engl. 49(17) , 3069-72, (2010)
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A SURGICAL APPROACH TO LARGE SUBRETINAL HEMORRHAGE USING PARS PLANA VITRECTOMY AND 360° RETINOTOMY.
Retina (Philadelphia, Pa.) 35 , 1631-9, (2015) To evaluate the surgical approach of pars plana vitrectomy combined with 360° retinotomy and silicon oil tamponade in the treatment of patients with large subretinal hemorrhage.Prospective, nonrandomized, and noncomparative case series study. Consecutive pati... |
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Long-term heavy silicone oil intraocular tamponade.
Int. Ophthalmol. 36 , 07-Mar, (2016) Heavy silicone oil tamponade is intended to be temporary, but may occasionally be indefinite in patients who refuse, or are deemed unsuitable for, further surgery. The aim of this study is to compare the outcomes of patients with temporary versus indefinite h... |
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Is bond stretch isomerism in mononuclear transition metal complexes a real issue? The misleading case of the MoCl5/tetrahydropyran reaction system.
Dalton Trans. 44 , 12653-9, (2015) Distinct batches of orange (1a-e) and green crystals (2a-e) were isolated from the reactions of MoCl5 with tetrahydropyran (thp), respectively at room temperature (in CH2Cl2) and at ca. 80 °C (in ClCH2CH2Cl). Crystals 2a-e are isomorphous to 1a-e and the IR s... |
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Contribution of postsynaptic T-type calcium channels to parallel fibre-Purkinje cell synaptic responses.
J. Physiol. 594 , 915-36, (2016) At the parallel fibre-Purkinje cell glutamatergic synapse, little or no Ca(2+) entry takes place through postsynaptic neurotransmitter receptors, although postsynaptic calcium increases are clearly involved in the synaptic plasticity. Postsynaptic voltage-gat... |
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An iodine catalyzed metal free domino process for the stereoselective synthesis of oxygen bridged bicyclic ethers.
Org. Biomol. Chem. 13 , 6737-41, (2015) A domino reaction has been developed for the synthesis of oxygen bridged bicyclic ethers through the coupling of 4-(2-hydroxyethyl)cyclohex-3-enols with aldehydes in the presence of 10 mol% of molecular iodine in dichloromethane at 25 °C. This method is highl... |
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A Maitland-Japp inspired synthesis of dihydropyran-4-ones and their stereoselective conversion to functionalised tetrahydropyran-4-ones.
Org. Biomol. Chem. 13(16) , 4743-50, (2015) The Maitland-Japp reaction has been extended to the synthesis of highly functionalised dihydropyran-4-ones. These dihydropyran-4-ones can in turn be converted stereoselectively into tetrahydropyran-4-ones with tertiary and quaternary stereocentres via the one... |
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Synthetic routes to tetrahydrofuran, tetrahydropyran, and spiroketal units of polyether antibiotics and a survey of spiroketals of other natural products. Boivin TLB.
Tetrahedron 43(15) , 3309-3362, (1987)
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Flame chemistry of tetrahydropyran as a model heteroatomic biofuel. Labbe NJ, et al.
Proc. Combust. Inst. 34(3) , 259-267, (2013)
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Samarium diiodide in tetrahydropyran: Preparation and some reactions in organic chemistry. Namy NJ, et al.
Tetrahedron Lett. 35(11) , 1723-1726, (1994)
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