十二羰基三钌
十二羰基三钌结构式
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常用名 | 十二羰基三钌 | 英文名 | Carbon monooxide-ruthenium (4:1) |
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| CAS号 | 15243-33-1 | 分子量 | 639.331 | |
| 密度 | N/A | 沸点 | N/A | |
| 分子式 | C12O12Ru3 | 熔点 | 150 °C | |
| MSDS | 中文版 美版 | 闪点 | N/A | |
| 符号 |
GHS07 |
信号词 | Warning |
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Ru-catalyzed intermolecular [3+2+1] cycloaddition of alpha,beta-unsaturated ketones with silylacetylenes and carbon monoxide leading to alpha-pyrones.
Org. Lett. 9 , 587, (2007) Ruthenium catalyzes a carbonylative [3+2+1] cycloaddition, using silylacetylenes, alpha,beta-unsaturated ketones, and CO as the starting materials, providing the new method for the synthesis of tetrasubstituted alpha-pyrones. In this reaction, the carbonyl gr... |
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