对伞花烃二氯化钌二聚体
对伞花烃二氯化钌二聚体结构式
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常用名 | 对伞花烃二氯化钌二聚体 | 英文名 | Dichloro(p-cymene)ruthenium(II) dimer |
|---|---|---|---|---|
| CAS号 | 52462-29-0 | 分子量 | 612.388 | |
| 密度 | N/A | 沸点 | 173.9ºC at 760mmHg | |
| 分子式 | C20H28Cl4Ru2 | 熔点 | 247.0-250.0 °C (dec.)(lit.) | |
| MSDS | 中文版 美版 | 闪点 | 47.2ºC | |
| 符号 |
GHS07 |
信号词 | Warning |
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Cyclometallation of arylimines and nitrogen-containing heterocycles via room-temperature C-H bond activation with arene ruthenium(II) acetate complexes.
Dalton Trans. 36th ed., 41 , 10934-10937, (2012) The reaction of [RuCl(2)(p-cymene)](2) with arylimines and 4 equiv. of KOAc in methanol at room temperature produces stable (N^C)-cyclometallated ruthenium(II) complexes via C-H bond activation/deprotonation. This method can be applied also to nitrogen-contai... |
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Ru-catalysed C-H arylation of indoles and pyrroles with boronic acids: scope and mechanistic studies.
Chemistry 21(14) , 5380-6, (2015) The Ru-catalysed C2-H arylation of indoles and pyrroles by using boronic acids under oxidative conditions is reported. This reaction can be applied to tryptophan derivatives and tolerates a wide range of functional groups on both coupling partners, including ... |
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