Dichloro(p-cymene)ruthenium(II) dimer
Dichloro(p-cymene)ruthenium(II) dimer structure
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Common Name | Dichloro(p-cymene)ruthenium(II) dimer | ||
|---|---|---|---|---|
| CAS Number | 52462-29-0 | Molecular Weight | 612.388 | |
| Density | N/A | Boiling Point | 173.9ºC at 760mmHg | |
| Molecular Formula | C20H28Cl4Ru2 | Melting Point | 247.0-250.0 °C (dec.)(lit.) | |
| MSDS | Chinese USA | Flash Point | 47.2ºC | |
| Symbol |
GHS07 |
Signal Word | Warning | |
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Cyclometallation of arylimines and nitrogen-containing heterocycles via room-temperature C-H bond activation with arene ruthenium(II) acetate complexes.
Dalton Trans. 36th ed., 41 , 10934-10937, (2012) The reaction of [RuCl(2)(p-cymene)](2) with arylimines and 4 equiv. of KOAc in methanol at room temperature produces stable (N^C)-cyclometallated ruthenium(II) complexes via C-H bond activation/deprotonation. This method can be applied also to nitrogen-contai... |
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Ru-catalysed C-H arylation of indoles and pyrroles with boronic acids: scope and mechanistic studies.
Chemistry 21(14) , 5380-6, (2015) The Ru-catalysed C2-H arylation of indoles and pyrroles by using boronic acids under oxidative conditions is reported. This reaction can be applied to tryptophan derivatives and tolerates a wide range of functional groups on both coupling partners, including ... |
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