4-氯苯酰甲基氯
4-氯苯酰甲基氯结构式
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常用名 | 4-氯苯酰甲基氯 | 英文名 | 2,4'-dichloroacetophenone |
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| CAS号 | 937-20-2 | 分子量 | 189.039 | |
| 密度 | 1.3±0.1 g/cm3 | 沸点 | 270.0±0.0 °C at 760 mmHg | |
| 分子式 | C8H6Cl2O | 熔点 | 100-102 °C(lit.) | |
| MSDS | 中文版 美版 | 闪点 | 119.1±21.0 °C | |
| 符号 |
GHS07 |
信号词 | Warning |
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Asymmetric hydrogenation of alpha-chloro aromatic ketones catalyzed by eta6-arene/TsDPEN-ruthenium(II) complexes.
Org. Lett. 9(2) , 255-257, (2007) Asymmetric hydrogenation of various alpha-chloro aromatic ketones with Ru(OTf)(TsDPEN)(eta6-arene) (TsDPEN = N-(p-toluenesulfonyl)-1,2-diphenylethylenediamine) produces the chiral chlorohydrins in up to 98% ee. This reaction can be conducted even on a 206-g s... |
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Purification and characterization of a yeast carbonyl reductase for synthesis of optically active (R)-styrene oxide derivatives.
Biosci. Biotechnol. Biochem. 69(1) , 79-86, (2005) Optically active styrene oxide derivatives are versatile chiral building blocks. Stereoselective reduction of phenacyl halide to chiral 2-halo-1-phenylethanol is the key reaction of the most economical synthetic route. Rhodotorula glutinis var. dairenensis IF... |
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Direct Investigation of Covalently Bound Chlorine in Organic Compounds by Solid-State 35Cl NMR Spectroscopy and Exact Spectral Line-Shape Simulations. Perras FA and Bryce DL.
Angew. Chem. Weinheim Bergstr. Ger. 124(11) , 4303-4306, (2012)
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Modified coumarins. 10. Synthesis of substituted 2-(7-oxofuro [3, 2-g] chromen-6-yl) acetic acids. Nagorichna IV, et al.
Chem. Nat. Cpds. 39(3) , 253-261, (2003)
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