2,4'-dichloroacetophenone

Modify Date: 2024-01-02 21:28:16

2,4'-dichloroacetophenone Structure
2,4'-dichloroacetophenone structure
Common Name 2,4'-dichloroacetophenone
CAS Number 937-20-2 Molecular Weight 189.039
Density 1.3±0.1 g/cm3 Boiling Point 270.0±0.0 °C at 760 mmHg
Molecular Formula C8H6Cl2O Melting Point 100-102 °C(lit.)
MSDS Chinese USA Flash Point 119.1±21.0 °C
Symbol GHS07
GHS07
Signal Word Warning

 Names

Name 2,4'-Dichloroacetophenone
Synonym More Synonyms

 Chemical & Physical Properties

Density 1.3±0.1 g/cm3
Boiling Point 270.0±0.0 °C at 760 mmHg
Melting Point 100-102 °C(lit.)
Molecular Formula C8H6Cl2O
Molecular Weight 189.039
Flash Point 119.1±21.0 °C
Exact Mass 187.979568
PSA 17.07000
LogP 2.53
Vapour Pressure 0.0±0.5 mmHg at 25°C
Index of Refraction 1.551

 Safety Information

Symbol GHS07
GHS07
Signal Word Warning
Hazard Statements H315-H319-H335
Precautionary Statements P261-P305 + P351 + P338
Personal Protective Equipment dust mask type N95 (US);Eyeshields;Gloves
Hazard Codes Xi:Irritant;
Risk Phrases R36/37/38
Safety Phrases S26-S36
RIDADR UN 3335
WGK Germany 3
HS Code 2914700090

 Synthetic Route

 Customs

HS Code 2914700090
Summary HS: 2914700090 halogenated, sulphonated, nitrated or nitrosated derivatives of ketones and quinones, whether or not with other oxygen function Tax rebate rate:9.0% Supervision conditions:none VAT:17.0% MFN tariff:5.5% General tariff:30.0%

 Articles4

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Asymmetric hydrogenation of various alpha-chloro aromatic ketones with Ru(OTf)(TsDPEN)(eta6-arene) (TsDPEN = N-(p-toluenesulfonyl)-1,2-diphenylethylenediamine) produces the chiral chlorohydrins in up ...

Purification and characterization of a yeast carbonyl reductase for synthesis of optically active (R)-styrene oxide derivatives.

Biosci. Biotechnol. Biochem. 69(1) , 79-86, (2005)

Optically active styrene oxide derivatives are versatile chiral building blocks. Stereoselective reduction of phenacyl halide to chiral 2-halo-1-phenylethanol is the key reaction of the most economica...

Direct Investigation of Covalently Bound Chlorine in Organic Compounds by Solid-State 35Cl NMR Spectroscopy and Exact Spectral Line-Shape Simulations. Perras FA and Bryce DL.

Angew. Chem. Weinheim Bergstr. Ger. 124(11) , 4303-4306, (2012)

 Synonyms

2,4'-dichloroacetophenone
Ethanone, 2-chloro-1-(4-chlorophenyl)-
MFCD00018926
2-Chloro-1-(4-chlorophenyl)ethanone
EINECS 213-323-9