2-(2-溴乙基)-1,3-二氧杂环乙烷
2-(2-溴乙基)-1,3-二氧杂环乙烷结构式
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常用名 | 2-(2-溴乙基)-1,3-二氧杂环乙烷 | 英文名 | 2-(2-Bromoethyl)-1,3-dioxane |
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| CAS号 | 33884-43-4 | 分子量 | 195.054 | |
| 密度 | 1.4±0.1 g/cm3 | 沸点 | 221.1±0.0 °C at 760 mmHg | |
| 分子式 | C6H11BrO2 | 熔点 | 157-161 °C | |
| MSDS | 中文版 美版 | 闪点 | 96.7±0.0 °C | |
| 符号 |
GHS07 |
信号词 | Warning |
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A rapid and general method for the asymmetric synthesis of 2-substituted pyrrolidines using tert-butanesulfinamide.
Org. Biomol. Chem. 3(11) , 2109-13, (2005) A new method for the asymmetric synthesis of 2-substituted pyrrolidines in three steps from commercially available starting materials is described. Addition of the Grignard reagent prepared from 2-(2-bromoethyl)-1,3-dioxane to N-tert-butanesulfinyl aldimines ... |
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Use of triphenylmethyl (trityl) amino protecting group in the synthesis of ketomethylene analogues of peptides.
Int. J. Pept. Protein Res. 23(6) , 581-90, (1984) The Grignard reagents of 2-(2-bromoethyl)-1,3-dioxane and 2-(2-bromoethyl)-1,3-dioxolane readily reacted with the 2-thiopyridyl ester of N-triphenylmethyl-L-leucine to give the ketone adducts 2-[3-oxo-4(S)-(triphenylmethyl) amino-6-methylheptyl]-1,3-dioxane (... |
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J.C. Stowell
J. Org. Chem. 41 , 560, (1976)
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Chem. Rev. 84 , 409, (1984)
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