2-(2-Bromoethyl)-1,3-dioxane
2-(2-Bromoethyl)-1,3-dioxane structure
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Common Name | 2-(2-Bromoethyl)-1,3-dioxane | ||
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| CAS Number | 33884-43-4 | Molecular Weight | 195.054 | |
| Density | 1.4±0.1 g/cm3 | Boiling Point | 221.1±0.0 °C at 760 mmHg | |
| Molecular Formula | C6H11BrO2 | Melting Point | 157-161 °C | |
| MSDS | Chinese USA | Flash Point | 96.7±0.0 °C | |
| Symbol |
GHS07 |
Signal Word | Warning | |
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A rapid and general method for the asymmetric synthesis of 2-substituted pyrrolidines using tert-butanesulfinamide.
Org. Biomol. Chem. 3(11) , 2109-13, (2005) A new method for the asymmetric synthesis of 2-substituted pyrrolidines in three steps from commercially available starting materials is described. Addition of the Grignard reagent prepared from 2-(2-bromoethyl)-1,3-dioxane to N-tert-butanesulfinyl aldimines ... |
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Use of triphenylmethyl (trityl) amino protecting group in the synthesis of ketomethylene analogues of peptides.
Int. J. Pept. Protein Res. 23(6) , 581-90, (1984) The Grignard reagents of 2-(2-bromoethyl)-1,3-dioxane and 2-(2-bromoethyl)-1,3-dioxolane readily reacted with the 2-thiopyridyl ester of N-triphenylmethyl-L-leucine to give the ketone adducts 2-[3-oxo-4(S)-(triphenylmethyl) amino-6-methylheptyl]-1,3-dioxane (... |
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J.C. Stowell
J. Org. Chem. 41 , 560, (1976)
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Chem. Rev. 84 , 409, (1984)
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